Chemistry of Natural Compounds

, Volume 17, Issue 6, pp 518–520 | Cite as

The structure of haploperoside B — An acylated coumarin glycoside fromHaplophyllum perforatum

  • M. P. Yuldashev
  • E. Kh. Batirov
  • V. M. Malikov
  • M. E. Perel'son


By chemical and spectral methods using INDOR the structure of an acylated coumarin glycoside, haploperoside B, isolated fromHaplophyllum perforatum has been established as 7-[2-0-[4-acetyl-α-L-rhamnopyranosyl)-β-D-glucopyranosyloxy]-6-methoxy-coumarin.


Rhamnose Flavanone Scopoletin Acetoxy Group Sodium Tetrahydroborate 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    M. P. Yuldashev, E. Kh. Batirov, and V. M. Malikov, Khim. Prir. Soedin., 412 (1980).Google Scholar
  2. 2.
    M. P. Yuldashev, E. Kh. Batirov, and V. M. Malikov, Khim. Prir. Soedin., 168 (1980).Google Scholar
  3. 3.
    B. Coxon, in: Methods in Carbohydrate Chemistry, Vol. 6, R. L. Whistler and J. N. BeMiller, eds., Academic Press, New York (1972), pp. 513–545.Google Scholar
  4. 4.
    R. U. Lemieux, R. K. Kulling, H. J. Bernstein, and W. G. Schneider, J. Am. Chem. Soc.,79, 1005 (1957);80, 6098 (1958).CrossRefGoogle Scholar
  5. 5.
    J. F. Stoddart, Stereochemistry of Carbohydrates, Interscience, New York (1971).Google Scholar
  6. 6.
    G. Kotowycz and R. U. Lemieux, Chem. Rev.,73, 669 (1973).CrossRefGoogle Scholar
  7. 7.
    L. D. Hall, Adv. Carbohydrate Chem.,19, 51 (1964).Google Scholar
  8. 8.
    H. Okabe and T. Kawasaki, Chem. Pharm. Bull.,20, 514 (1972).CrossRefGoogle Scholar
  9. 9.
    D. Brown, R. O. Asplund, and V. A. McMahon, Phytochemistry,13, 1923 (1974).CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • M. P. Yuldashev
  • E. Kh. Batirov
  • V. M. Malikov
  • M. E. Perel'son

There are no affiliations available

Personalised recommendations