Conclusions
Digoxigenin 3-(α-L-rhamnopyranoside) has been synthesized from digoxigenin and L-rhamnose with a yield of 37%; it has been shown that in the condensation of acetylrhamnosyl bromide with the agylcone practically no reaction takes place at the C12 hydrdroxyl because of steric hindrance.
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Khimiya Prirodnykh Soedinenii, Vol. 4, No. 6, pp. 358–360, 1968
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Makarevich, I.F., Chub, V.F. Digoxigenin 3-α-L-rhamnoside. Chem Nat Compd 4, 302–303 (1968). https://doi.org/10.1007/BF00569809
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DOI: https://doi.org/10.1007/BF00569809