Summary
1. The chemical shifts and spin-spin coupling constants of the protons of the alkaloid haplophyllidine in 12 solvents have been studied.
2. It has been shown that in deuteropyridine the signals are located in a weaker field than in deuterobenzene.
3. The protons of the furan ring undergo the strongest influence of solvents.
Similar content being viewed by others
Literature cited
A. D. Buckingham, T. Schaefer, and W. G. Schneider, J. Chem. Phys.,32, 1227 (1960).
P. Laszlo, Progr. Nuclear Magnetic Resonance Spectroscopy,3, 231 (1957).
M. D. Johnston, Jr., and M. Barfield, J. Chem. Phys.,54, 3083 (1971).
R. Ottinger, A. Boulvin, J. Reisse, and A. Chiurdoglu, Tetrahedron,21, 3435 (1965).
G. S. Ricca and B. Danieli, Gazz. Chim. Italiana,99, 133 (1969).
T. Shakirov, G. P. Sidyakin, and S. Yu. Yunusov, Dokl. Akad. Nauk UzSSR, No. 6, 28 (1959).
I. A. Bessonova, Z. Sh. Faizutdinova, Ya. V. Rashkes, M. R. Yagudaev, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 273 (1969).
D. H. Williams and D. A. Wilson, J. Chem. Soc., B, No. 2, 144 (1966).
J. Ronayne and D. H. Williams, J. Chem. Soc., B, No. 5, 540 (1967).
R. M. Moriarty, J. Org. Chem.,23, 1296 (1963).
J. V. Hatton and R. E. Richards, Mol. Phys.,5, 153 (1962).
D. H. Williams, Tetrahedron Lett.,27, 2305 (1965).
L. Onsager, J. Amer. Chem. Soc.,58, 1486 (1936).
A. D. Buckingham, Can. J. Chem.,38, 300 (1960).
R. E. Klinck and J. B. Stothers, Canad. J. Chem.,40, 2329 (1962).
T. Schaefer and W. G. Schneider, J. Chem. Phys.,32, 1218 (1960).
R. G. Wilson and D. H. Williams, J. Chem. Soc., C, No. 19, 2475 (1968).
H. M. Hutton and T. Schaefer, Canad. J. Chem.,43, 3116 (1965).
V. S. Watts and J. H. Goldstein, J. Chem. Phys.,42, 228 (1965).
K. A. McLanchlan, J. W. Reever, and T. Schaefer, Canad. J. Chem.,44, 1473 (1966).
C. J. Macdonald and T. Schaefer, Canad. J. Chem.,45, 3157 (1967).
S. L. Smith and R. H. Cox, J. Chem. Phys.,45, 2848 (1966).
S. L. Smith and A. M. Ihrig, J. Chem. Phys.,46, 1181 (1967).
P. Bates, S. Cawley, and S. S. Danyluk, J. Chem. Phys.,20, 2415 (1964).
R. H. Cox and J. W. Harrison, J. Magn. Res., 684 (1972).
Additional information
Institute of Plant Substances, Academy of Sciences of the Uzbek SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 507–510, July–August, 1973.
Rights and permissions
About this article
Cite this article
Seitanidi, K.L., Yagudaev, M.R. & Yunusov, S.Y. Influence of solvents on the chemical shifts and spin - spin coupling constants of protons in alkaloids I. Haplophyllidine. Chem Nat Compd 9, 477–480 (1973). https://doi.org/10.1007/BF00568634
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00568634