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Mass-spectrometric study of the structure of the alkaloids of lolium

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Chemistry of Natural Compounds Aims and scope

Conclusions

1. The results of a study of the fragmentation of substances (I)-(IX) under the conditions of mass spectroscopy have confirmed the positions of the side-chain nitrogen atom and the ethereal oxygen.

2. When the functional groups in position C1 in the molecules of substances (I)-(IX) change, the main fragments remain the same for all the compounds studied and specific fragments appear for each compound.

3. A possible scheme of fragmentation is given for substances (I)-(IX).

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Khimiya Prirodynkh Soedinenii, Vol. 4, No. 5, pp. 298–304, 1968

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Akramov, S.T., Yunusov, S.Y. Mass-spectrometric study of the structure of the alkaloids of lolium. Chem Nat Compd 4, 252–256 (1968). https://doi.org/10.1007/BF00568531

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  • DOI: https://doi.org/10.1007/BF00568531

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