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Chemistry of Natural Compounds

, Volume 17, Issue 3, pp 213–217 | Cite as

Identification of aliphatic 2- and 3-hydroxy acids in the form of cyclic phenylboronates by GLC-mass spectrometry

  • S. G. Batrakov
  • B. V. Rozynov
  • A. N. Ushakov
Article
  • 21 Downloads

Abstract

A method is prepared for identifying aliphatic 2- and 3-hydroxy acids which is based on the GLC-mass spectrometry of the corresponding phenylboronates. The phenyl-boronates are sufficiently volatile for analysis with the aid of GLC and give simple and informative mass spectra.

Keywords

Decanoic Acid Phenylboronic Acid Anhydrous Dioxane Cyclic Derivative Alkyl Residue 

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Literature cited

  1. 1.
    Bacterial Lipopolysaccharides, E. H. Kass and S. M. Wolff, eds., University Press, Chicago (1973).Google Scholar
  2. 2.
    C. Hitchcock, Biochem. J.,103, 8P (1967).Google Scholar
  3. 3.
    A. Ya. Veinberg, L. A. Vakulova, and G. I. Samokhvalov, Usp. Khim.,35, 2072 (1966).CrossRefGoogle Scholar
  4. 4.
    S. G. Batrakov and L. D. Bergelson, Chem. Phys. Lipids,21, 1 (1978).CrossRefPubMedPubMedCentralGoogle Scholar
  5. 5.
    I. Yano, Y. Furukawa, and M. Kusunose, FEBS Lett.,4, 96 (1969).CrossRefPubMedPubMedCentralGoogle Scholar
  6. 6.
    C. W. Moss and S. B. Dees, J. Chromatogr.,112, 595 (1975).CrossRefGoogle Scholar
  7. 7.
    J. S. O'Brien and G. Rouser, Anal. Biochem.,7, 288 (1964).CrossRefGoogle Scholar
  8. 8.
    R. D. Wood, P. K. Raju, and R. Reiser, J. Am. Oil. Chem. Soc.,42, 81 (1965).CrossRefGoogle Scholar
  9. 9.
    R. A. Laine, N. D. Young, J. N. Gelber, and C. C. Sweeley, Biomed. Mass Spectrom.,1, 10 (1974).CrossRefPubMedGoogle Scholar
  10. 10.
    R. Ryhage and E. Stenhagen, Ark. Kem.,15, 545 (1960).Google Scholar
  11. 11.
    C. F. Poole and A. Zlatkis, J. Chromatogr.,184, 99 (1980).CrossRefGoogle Scholar
  12. 12.
    S. G. Batrakov, A. N. Ushakov, and V. L. Sadovskaya, Bioorg. Khim.,2, 1095 (1976).Google Scholar
  13. 13.
    C. J. W. Brooks and J. Maclean, J. Chromatogr. Sci.,9, 19 (1971).CrossRefGoogle Scholar
  14. 14.
    I. R. McKinley and H. Weigel, Chem. Commun., 1022 (1970).Google Scholar
  15. 15.
    I. R. McKinley and H. Weigel, Chem. Commun., 1051 (1972).Google Scholar
  16. 16.
    S. G. Batrakov, E. F. Il'ina, B. V. Rozynov, V. L. Sadovskaya, and L. D. Bergel'son, Izv. Akad. Nauk SSSR, Ser. Khim., 821 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • S. G. Batrakov
  • B. V. Rozynov
  • A. N. Ushakov

There are no affiliations available

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