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Structure and configuration of the coumarins mogoltadone and mogoltadin

Chemistry of Natural Compounds Aims and scope

Conclusions

Two new terpenoid coumarins — mogoltadone and mogoltadin — have been isolated from the roots ofFerula mogoltavica. Mogoltadone has the composition C24H28O4, [α] 21D -41.7° (c 1.1; chloroform). On the basis of spectral characteristics, it has been shown that it is the ether of umbelliferone and 3-oxo-4,4,10-trimethyl-8-vinyldecalin-9-ylmethanol with the trans linkage of rings A and B and the equatorial orientation of the substituent at C9. Mogoltadin has the composition C24H30O4, [α] 21D -55° (c 1.0; ethanol) and is the ether of umbelliferone and 3-hydroxy-4,4,10-trimethyl-8-vinyldecalin-9-ylmethanol with the trans linkage of rings A and B and the diequatorial arrangement of the substituents at C3 and C9.

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Literature cited

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Order of the Red Banner of Labor Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 25–29, January–February, 1974.

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Khasanov, T.K., Saidkhodzhaev, A.I. & Nikonov, G.K. Structure and configuration of the coumarins mogoltadone and mogoltadin. Chem Nat Compd 10, 20–23 (1974). https://doi.org/10.1007/BF00568212

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  • DOI: https://doi.org/10.1007/BF00568212

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