Summary
1. The nitrobenzene oxidation of the natural lignins of kenaf stems and of DLA fractions has been performed. A study of the oxidation products by gas-liquid chromatography has shown that the kenaf lignins are constructed of three types of structural units: p-coumaryl, guaiacyl, and syringyl, with the latter predominating.
2. Among the products of the nitrobenzene oxidation of fractions of kenaf dioxane lignin paper chromatography has shown the presence of dihydrodivanillin, which is a representative of structures with a biphenyl bond.
Similar content being viewed by others
Literature cited
N. Ya. Kul'chik, G. N. Dalimova, and Kh. A. Abduazimov, Khim. Prirodn. Soedin., 637 (1978) [preceding paper in this issue].
B. Leopold, Acta Chem. Scand.,4, 1523 (1950).
K. K. Lebedev, Collected Works [in Russian], No. 16, Moscow (1965), p. 58.
I. Z. Kirshbaum, G. E. Sharapova, G. V. Dobele, and T. É. Domburg, Khim. Drev., No. 1, 39 (1975).
R. D. Hartley, J. Chromatogr.,54, 335 (1971).
K. J. Harrington and J. Hamilton, Can. J. Chem.,48, 2607 (1970).
A. A. Geronikaki and Kh. A. Abduazimov, Khim. Prirodn. Soedin., 93 (1977).
N. A. Veksler, L. S. Smirnova, and Kh. A. Abduazimov, Khim. Prirodn. Soedin., 100 (1977).
B. J. Fergus and D. A. Goring, Holzforschung,24, No. 4, 113 (1970).
B. Leopold, Acta Chem. Scand.,6, 38 (1952).
J. A. Pearl, J. Am. Chem. Soc.,72, 2309 (1950).
L. A. Kodina and V. N. Generalova, Zh. Prikl. Khim.,12, 2717 (1968).
J. C. Pew, J. Am. Chem. Soc.,77, 2831 (1955).
H. McNair and E. Bonelli, Basic Gas Chromatography, 4th ed., Varian Aerograph, Walnut Creek, Calif. (1968).
Additional information
Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 641–645, September–October, 1978.
Rights and permissions
About this article
Cite this article
Geronikaki, A.A., Dalimova, G.N., Kul'chik, N.Y. et al. A study of the structure of kenaf lignins by alkaline nitrobenzene oxidation. Chem Nat Compd 14, 551–554 (1978). https://doi.org/10.1007/BF00567154
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00567154