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Chemistry of Natural Compounds

, Volume 11, Issue 4, pp 503–505 | Cite as

Mass spectrometry of gibberellins III. Features of the fragmentation of 3 α-hydroxy and 3-keto derivatives of the gibberellin series

  • É. P. Serebryakov
  • N. S. Kobrina
  • B. V. Rozynov
Article
  • 29 Downloads

Summary

In the mass spectrum of the 3 α-epimer of the methyl ester of gibberellin As there is an increased intensity of the peaks connected with the elimination of the lactone ring. For the 3-keto derivatives of the gibberellin A1 series with substituents at C1 the formation of ions corresponding to the splitting out of the C1-C2-C3 fragment is characteristic.

Keywords

Methyl Ester Gibberellin Fragmentation Pathway Lactone Ring Chromium Trioxide 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • É. P. Serebryakov
  • N. S. Kobrina
  • B. V. Rozynov

There are no affiliations available

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