Summary
On the basis of the results of a study of the products of chemical transformations and spectra, the structure of angrendiol has been established as 4,8-dihydroxygermacra-1(10), 5(6)-diene. It has been shown that ferolin and chimganidin are monoesters of angrendiol with parahydroxybenzoic and vanillic acids, respectively, at the secondary hydroxy group.
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T. Kh. Khasanov, A. I. Saidkhodzhaev, and G. K. Nikonov, Khim. Prirodn. Soedin., 807 (1972).
A. Sh. Kadyrov, T. Kh. Khasanov, A. I. Saidkhodzhaev, and G. K. Nikonov, Khim. Prirodn. Soedin., 808 (1972).
N. P. Kir'yalov, Trudy BIN SSSR,15, 129 (1970).
C. N. O. Rao, Ultra-Violet and Visible Spectroscopy. Chemical Applications, 1st ed., Butterworth, London (1961).
E. D. Brown and J. K. Sutherland, Chem. Commun., 1060 (1968).
E. D. Brown, W. D. Solomon, J. K. Sutherland, and A. Torre, Chem. Commun., 111 (1967).
K. Wada and K. Munakata, Tetrahedron Lett., No. 45, 4677 (1968).
K. Takeda, Tetrahedron,30, 1525 (1974).
K. Takeda, J. Horibe, and H. Minato, J. Chem. Soc., (C), 1142 (1970).
G. H. Kulkarni, G. R. Kelkar, and S. C. Bhattacharyya, Tetrahedron,20, 1301 (1964).
G. V. Smith and H. Kriloff, J. Am. Chem. Soc.,85, 2016 (1963).
Additional information
Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 519–525, July–August, 1977.
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Saidkhodzhaev, A.I., Abdullaev, N.D., Khasanov, T.K. et al. Structures of angrendiol, ferolin, and chimganidin. Chem Nat Compd 13, 434–438 (1977). https://doi.org/10.1007/BF00565830
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DOI: https://doi.org/10.1007/BF00565830