Use of the paramagnetic shift agent Eu(DPM)3 for studying the structure and stereochemistry of conferol and conferone
On the basis of a study of the NMR spectra of conferol with additions of Eu(DPM)3 the molecular structure proposed for it previously has been confirmed, and two variants of the relative configuration have been given. Conferone has the analogous structure with the oxo group in position 6.
KeywordsHMDS Relative Configuration Hydroxyl Oxygen Decalin Paramagnetic Shift
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