Chemistry of Natural Compounds

, Volume 4, Issue 3, pp 145–149 | Cite as

Structure of petiline

  • R. N. Nuriddinov
  • B. Babaev
  • S. Yu. Yunusov


1. Imperialine, edpetilidine, and the new alkaloid petiline C27H43O2N have been isolated from the epigeal part ofP. raddeana.

2. On the basis of a study of the chemical properties and the IR, UV, NMR, and mass spectra a most probable structure and a partial configuration have been proposed for petiline.


Double Bond Alkaloid Carbonyl Group Acetic Anhydride Hydrobromide 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    H. G. Boit, Ber.,87, 472, 1954.Google Scholar
  2. 2.
    H. G. Boit and L. Paul., Ber.,90, 723, 1957.Google Scholar
  3. 3.
    T. T. Chu and J. Y. Lon, Acta Chim. Sinica,21, 241, 1955.Google Scholar
  4. 4.
    T. T. Chu and J. Y. Lon, Acta Chim. Sinica,22, 210, 356, 1956.Google Scholar
  5. 5.
    T. T. Chu, J. Y. Lon, and W. K. Hwang, Acta Chim. Sinica,21, 401, 1955.Google Scholar
  6. 6.
    T. T. Chu, J. Y. Lon, and W. K. Hwang, Acta Chim. Sinica,22, 205, 1956.Google Scholar
  7. 7.
    R. N. Nuriddinov and S. Yu. Yunusov, DAN UzSSR, no. 4, 33, 1961.Google Scholar
  8. 8.
    R. N. Nuriddinov and S. Yu. Yunusov, DNA UzSSR, no. 5, 47, 1962.Google Scholar
  9. 9.
    R. N. Nuriddinov, R. Shakirov, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],3, 316, 1967.Google Scholar
  10. 10.
    R. Shakirov, R. N. Nuriddinov, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],1, 384, 1965.Google Scholar
  11. 11.
    W. A. Jacobs and N. Sato, J. biol. Chem.,175, 57, 1948.PubMedGoogle Scholar
  12. 12.
    W. A. Jacobs and C. F. Huebner, J. biol. Chem.,170, 635, 1947.Google Scholar
  13. 13.
    H. G. Boit, Ergebnisse der Alkaloid-Chemie, 758–832, 1962.Google Scholar
  14. 14.
    R. F. Zürcher, Helv. Chim. Acta,46, 2054, 1963.CrossRefGoogle Scholar
  15. 15.
    P. M. Boll, Acta Chem. Scand.,19, 1365, 1965.CrossRefGoogle Scholar
  16. 16.
    T. Masamune, Y. Mori, M. Takasugi, and A. Murai, Tetrah. Lett.,16, 913, 1964.CrossRefGoogle Scholar
  17. 17.
    T. Masamune, M. Takasugi, and Y. Mori, Tetrah. Lett.,9, 489, 1965.CrossRefGoogle Scholar
  18. 18.
    T. Masamune, M. Takasugi, M. Gohda, H. Suzuki, S. Kawahara, and T. Irie, J. Org. Chem.,29, 2282, 1964.CrossRefGoogle Scholar
  19. 19.
    T. Masamune, N. Sato, K. Kobayashi, J. Yamazaki, and Y. Mori, Tetrah.,23, 1591, 1967.CrossRefGoogle Scholar
  20. 20.
    S. Ito, J. B. Stothers, and S. M. Kupchan, Tetrah.,20, 913, 1964.CrossRefGoogle Scholar
  21. 21.
    W. G. Craig, P. V. Demarco, D. W. Mathieson, L. Saunders, and W. B. Whalley, Tetrah.,23, 2357, 1967.CrossRefGoogle Scholar
  22. 22.
    H. Budzikiewicz, Tetrah.,20, 2267, 1964.CrossRefGoogle Scholar

Copyright information

© The Faraday Press, Inc. 1971

Authors and Affiliations

  • R. N. Nuriddinov
    • 1
  • B. Babaev
    • 1
  • S. Yu. Yunusov
    • 1
  1. 1.Institute of the Chemistry of Plant Substances AS UzSSRUSSR

Personalised recommendations