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Chemistry of Natural Compounds

, Volume 6, Issue 6, pp 724–727 | Cite as

The polybuffer separation of the alkaloids of Vinca erecta

  • D. A. Rakhimov
  • M. R. Sharipov
  • Kh. N. Aripov
  • V. M. Malikov
  • T. T. Shakirov
  • S. Yu. Yunusov
Article

Summary

By separating the total alkaloids ofV.erecta according to their basicities in an APS, in addition to bases known previously we have isolated ervincidine, apovincamine, (+)-quebrachamine, dl-eburnamine, (−)-1,2-dehydroaspidospermidine, and kopsanone. This is the first time that these alkaloids have been obtained from this plant. Thin-layer chromatography showed the presence of another 10–12 uncharacterized alkaloids.

The region of the passage into the buffer solutions of some alkaloids has also been established.

Keywords

Alkaloid Total Alkaloid Vincamine Caustic Potash Petroleum Ether Fraction 

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Literature cited

  1. 1.
    S. Yu. Yunusov, Alkaloids [in Russian], Tashkent, 1968, p. 135.Google Scholar
  2. 2.
    S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],6, 149, 1970.Google Scholar
  3. 3.
    L. I. Brutko, G. F. Alyabina, and M. A. Romanchuk, Khim.-Farm-Zh.,2, 54, 1968.Google Scholar
  4. 4.
    Sh. Z. Kasymov, Kh. N. Aripov, T. T. Shakirov, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],3, 352, 1967.Google Scholar
  5. 5.
    V. M. Malikov, P. Kh. Yuldashev, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],2, 338, 1966.Google Scholar
  6. 6.
    N. Abdurakhimova, P. Kh. Yuldashev, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],3, 310, 1967.CrossRefGoogle Scholar
  7. 7.
    M. Plat, Duc Dohkac, J. LeMen, M. Janot, H. Budzikiewicz, M. Wilson, L. Durham, and C. Djerassi, Bull. 1082, 1962.Google Scholar
  8. 8.
    H. F. Manske, The Alkaloids, Vol. VIII, 1965, p. 378.Google Scholar
  9. 9.
    F. Walls, O. Collera, and A. Sandoval, Tetrah.,2, 173 (1958).CrossRefGoogle Scholar
  10. 10.
    H. Budzikiewicz, C. Djerassi, and D. H. Williams, Structure Elucidation of Natural Products by Mass Spectrometry, Vol. I, Alkaloids, Holden—Day, San Francisco, 1964, p. 47.Google Scholar
  11. 11.
    D. A. Rakhimov, V. M. Malikov, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds],3, 354, 1967.Google Scholar
  12. 12.
    J. M. Ferriera Filho, B. Gilbert, M. Kitagawa, L. A. Paes Leme, and Lois J. Durham, J. Chem. Soc. C, No. 4, 1260, 1966.Google Scholar
  13. 13.
    H. Achenbach, K. Biemann, J. Amer. Chem. Soc., 87, 4944, 1965.CrossRefGoogle Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1973

Authors and Affiliations

  • D. A. Rakhimov
  • M. R. Sharipov
  • Kh. N. Aripov
  • V. M. Malikov
  • T. T. Shakirov
  • S. Yu. Yunusov

There are no affiliations available

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