Skip to main content
Log in

A comparative study of the IR spectra of alkaloids containing piperidine and quinolizidine rings in the 2500–2830 cm−1 region

  • Published:
Chemistry of Natural Compounds Aims and scope

Summary

1. A comparative method of studying the conformational states of alkaloids of the piperidine and quinolizidine series by comparing the intensities of the IR bands in the 2500–2830 cm−1 region in the solid and liquid states has been proposed.

2. It has been shown that the process of inversion and other labile conformational transformations affect the number, frequency, and intensity of the vibrational transitions in the “Bohlmann region.”

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. F. Bohlmann, Ber.,91, 2157 (1958).

    CAS  Google Scholar 

  2. M. Wiewiorowski and I. Skolik, Bull. Acad. Polon. Sci., Ser. Sci. Chim.,1, 10 (1962).

    Google Scholar 

  3. M. Wiewiorowski, O. E. Edwards, and T. D. Bratek-Wiewiorowska, Canad. J. Chem.,45, 1447 (1967).

    Article  CAS  Google Scholar 

  4. I. Skolik, P. I. Krueger, and M. Wiewiorowski, Tetrahedron,24, 5439 (1968).

    Article  CAS  Google Scholar 

  5. M. Masamune and M. Takasuga, Chem. Commun.,13, 623 (1967).

    Google Scholar 

  6. F. Bohlmann, D. Schumann, and C. Arndt, Tetrahedron,31, 2705 (1965).

    Article  Google Scholar 

  7. A. P. Matveeva, T. K. Yunusov, V. B. Leont'ev, Kh. A. Aslanov, and A. S. Sadykov, Abstracts of Lectures at the 7th International Symposium on the Chemistry of Natural Compounds [in Russian], Riga (1970).

  8. T. K. Yunusov, A. I. Ishbaev, V. B. Leont'ev, and A. S. Sadykov, Khim. Prirodn. Soedin., 49 (1971).

  9. R. N. Jones, D. A. Ramsay, D. S. Keir, and K. Dobriner, J. Amer. Chem. Soc.,74, 80 (1952).

    Article  CAS  Google Scholar 

  10. M. Aroney and R. J. Le Fèvre, J. Chém. Soc.,1958, 3002.

  11. O. S. Anisimova, A. N. Kost, Yu. A. Pentin, and L. G. Yudin, Vestn. Mosk. Univ., Seriya Khim.,1966, No. 4, 19.

  12. N. I. Bogdanskis and M. O. Bulanin, Opt. i Spektroskopiya,19, No. 2, 229 (1965).

    Google Scholar 

  13. E. Eliel, N. Allinger, S. Angyal, and G. Morrison, Conformational Analysis, Interscience, New York (1969).

    Google Scholar 

Download references

Authors

Additional information

V. I. Lenin Tashkent State University. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 200–207, March–April, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yunusov, T.K., Matveeva, A.P., Leont'ev, V.B. et al. A comparative study of the IR spectra of alkaloids containing piperidine and quinolizidine rings in the 2500–2830 cm−1 region. Chem Nat Compd 8, 201–206 (1972). https://doi.org/10.1007/BF00565300

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00565300

Keywords

Navigation