Abstract
A fairly simple and original one-stage method of obtaining optically active attractants ofPorthetria dispar-(+)- and (-)-2-methyl-Z- and E-7,8-epoxyoctadecanes has been developed. The synthesis is based on the epoxidation of 2-methyloctadec-Z-and -E-7-enes by chiral peroxide complexes of molybdenum of the type of MoO3-L* in an organic solvent at room temperature. Derivatives of tartaric, lactic, β-aminopropionic, and aspartic acids have been used as the chiral ligands (L*).
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Institute of Chemistry of the Bashkir Branch of the Academy of Sciences of the USSR, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 5, p. 650–657, September–October, 1981.
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Dzhemilev, U.M., Fakhretdinov, R.N., Telin, A.G. et al. A new approach to the synthesis of optically active disparlures — Attractants ofPorthetria dispar . Chem Nat Compd 17, 482–487 (1981). https://doi.org/10.1007/BF00565169
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DOI: https://doi.org/10.1007/BF00565169