Abstract
From the roots ofPeucedanum mogoltavicum Korov. have been isolated tadzhiferin, farnesiferol B, 5-methoxy-3,4-methylenedioxypropiophenone, and a new terpenoid coumarin — tavimolidin. The structure and absolute configuration of tavimolidin have been established on the basis of a study of its chemical and spectral characteristics. The passage from tavimolidin to feselol has confirmed the structure proposed previously for mogoltavinin, mogoltavin, and mogoltin and has established their absolute configurations.
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Literature cited
A. Sh. Kadyrov and G. N. Nikonov, Khim. Prir. Soedin., 107 (1973).
V. Yu. Bagirov, Khim. Prir. Soedin., 688 (1973).
M. E. Perel'son, V. V. Vandyshev, Yu. E. Sklyar, K. Vezhkhovska-Renke, N. V. Veselovskaya, and M. G. Pimenov, Khim. Prir. Soedin., 593 (1976).
L. Caglioti, H. Naef, D. Arigoni, and O. Jeger, Helv. Chim. Acta,42, 2557 (1959).
Kh. M. Kamilov and G. K. Nikonov. Khim. Prir. Soedin., 443 (1974).
G. K. Nikonov and V. B. Kuvaev, Zh. Obshch. Khim.,34, No. 3, 1020 (1964).
G. K. Nikonov, Khim. Prir. Soedin., 54 (1972).
Yu. E. Sklyar, M. E. Perel'son, and M. G. Pimenov, Khim. Prir. Soedin., 428 (1973).
N. P. Kir'yalov and T. V. Bukreeva, Khim. Prir. Soedin., 425 (1973).
M. E. Perel'son, N. P. Kir'yalov, and A. I. Ban'kovskii, Khim. Prir. Soedin., 244 (1975).
M. E. Perel'son, A. A. Kir'yalov, A. I. Ban'kovskii, N. P. Kir'yalov, and T. V. Bukreeva, Khim. Prir. Soedin., 442 (1976).
M. Pinar and B. Rodriguez, Phytochemistry,16, 1987 (1976).
Huang-Minlon, J. Am. Chem. Soc.,71, 3301 (1949).
R. Bartoszewicz, W. Miecznikowska-Stolarczyk, and B. Oprzadek, Methods of Reducing Organic Compounds [in Russian], Moscow (1960), p. 278.
G. K. Nikonov, Khim. Prir. Soedin., 43 (1972); 572 (1971).
A. A. Nabiev, T. Kh. Khasanov, and V. M. Malikov, Khim. Prir. Soedin., 17 (1979).
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Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Pridornykh Soedinenii, No. 4, pp. 480–483, July–August, 1979.
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Khasanov, T.K., Malikov, V.M. & Melibaev, S. Structure and configuration of tavimolidin. Chem Nat Compd 15, 417–419 (1979). https://doi.org/10.1007/BF00565036
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DOI: https://doi.org/10.1007/BF00565036