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Chemistry of Natural Compounds

, Volume 12, Issue 6, pp 702–705 | Cite as

The structure of regeline

  • D. A. Abdullaeva
  • M. K. Yusupov
  • Kh. A. Aslanov
Article

Summary

On the basis of a study of spectra and chemical transformations the structure of 11-hydroxy-2,12-dimethoxy-1,12-epoxyhexahydrohomoproaporphine has been proposed for regeline — a base fromColchicum kesselringii Rgl.

The homoproaporphine carbon-nitrogen skeleton and the complete structure of regeline have been confirmed by a study of its13C NMR spectrum.

Keywords

Acetic Anhydride Acetyl Chloride Caustic Soda Methylene Carbon Hydrogen Chloride 

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Literature cited

  1. 1.
    M. K. Yusupov, in: The Chemistry of Plant Substances [in Russian], Tashkent (1972), p. 19.Google Scholar
  2. 2.
    K. Bernauer and W. Hofheinz, Fortschr. Chem. Org. Naturstoffe, 245 (1968).Google Scholar
  3. 3.
    K. L. Stuart and M. P. Cava, Chem. Rev.,68, 321 (1968).CrossRefGoogle Scholar
  4. 4.
    L. Dolejs, Collection Czech. Chem. Commun.,39, 571 (1974).CrossRefGoogle Scholar
  5. 5.
    M. K. Yusupov, D. A. Abdullaeva, Kh. A. Aslanov, and A. S. Sadykov, Khim. Prirodn. Soedin., 383 (1974).Google Scholar
  6. 6.
    F. Santavy, P. Sedmera, G. Snatzke, and T. Reichstein, Helv. Chim. Acta,54, 1084 (1971).CrossRefGoogle Scholar
  7. 7.
    A. P. Orekhov, The Chemistry of the Alkaloids [in Russian], Moscow (1955), p. 254.Google Scholar
  8. 8.
    A. K. Kasimov, M. K. Yusupov, E. Kh. Timbekov, and Kh. A. Aslanov, Khim. Prirodn. Soedin., 194 (1975).Google Scholar
  9. 9.
    E. Kh. Timbekov, A. K. Kasimov, D. A. Abdullaeva, M. K. Yusupov, and Kh. A. Aslanov, Khim. Prirodn. Soedin., 327 (1976).Google Scholar
  10. 10.
    M. K. Yusupov, D. A. Abdullaeva, Kh. A. Aslanov, and A. S. Sadykov, Khim. Prirodn. Soedin., 383 (1975).Google Scholar
  11. 11.
    M. K. Yusupov and A. S. Sadykov, Khim. Prirodn. Soedin., 349 (1976).Google Scholar
  12. 12.
    M. K. Yusupov, D. A. Abdullaeva, F. G. Kamaev, and A. S. Sadykov, Dokl. Akad. Nauk UzSSR, No. 2, 51 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • D. A. Abdullaeva
  • M. K. Yusupov
  • Kh. A. Aslanov

There are no affiliations available

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