Summary
Under the action of catalytic amounts of mineral acid, the pentaol obtained by the reduction of the norditerpenoid teucrin A with lithium tetrahydroaluminate undergoes an anionotropic rearrangement with the subsequent elimination of a molecule of water.
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Literature cited
D. P. Popa and A. M. Reinbol'd, Khim. Prirodn. Soedin., 31 (1973).
C. Kaneko, T. Tsuchiya and M. Ishikawai, Chem. Pharm. Bull.,11, 271 (1963).
K. Nakanishi, Infrared Absorption Spectroscopy. Practical, Holden-Day, San Francisco (1962).
Additional information
Institute of Chemistry, Academy of Sciences of the Moldavian SSR, Kishinev. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 752–757, November–December, 1976.
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Reinbol'd, A.M., Popa, D.P. Anionotropic rearrangement in a series of derivatives of teucrin A. Chem Nat Compd 12, 675–679 (1976). https://doi.org/10.1007/BF00564957
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DOI: https://doi.org/10.1007/BF00564957