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Anionotropic rearrangement in a series of derivatives of teucrin A

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Summary

Under the action of catalytic amounts of mineral acid, the pentaol obtained by the reduction of the norditerpenoid teucrin A with lithium tetrahydroaluminate undergoes an anionotropic rearrangement with the subsequent elimination of a molecule of water.

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Literature cited

  1. D. P. Popa and A. M. Reinbol'd, Khim. Prirodn. Soedin., 31 (1973).

  2. C. Kaneko, T. Tsuchiya and M. Ishikawai, Chem. Pharm. Bull.,11, 271 (1963).

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  3. K. Nakanishi, Infrared Absorption Spectroscopy. Practical, Holden-Day, San Francisco (1962).

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Institute of Chemistry, Academy of Sciences of the Moldavian SSR, Kishinev. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 752–757, November–December, 1976.

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Reinbol'd, A.M., Popa, D.P. Anionotropic rearrangement in a series of derivatives of teucrin A. Chem Nat Compd 12, 675–679 (1976). https://doi.org/10.1007/BF00564957

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  • DOI: https://doi.org/10.1007/BF00564957

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