Chemistry of Natural Compounds

, Volume 8, Issue 6, pp 708–712 | Cite as

NMR spectra, structure, and stereochemistry of grossheimin

  • V. I. Sheichenko
  • K. S. Rybalko


1. The chemical shifts and coupling constants of all the protons in the grossheimin molecule have been found with the aid of double and triple resonance and also by the INDOR method.

2. The position of the oxo group at C2 in grossheimin has been confirmed.

3. The configuration and conformation of the grossheimin molecules have been determined.


Dihedral Angle Lactone Ring INDOR Method Lactone Proton Allyl Proton 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    K. S. Rybalko and V. I. Sheichenko, Zh. Obshch. Khim.,35, No. 3, 580 (1965).Google Scholar
  2. 2.
    M. N. Mukhametzhanov V. I. Sheichenko, K. S. Rybalko, and K. I. Boryaev, Khim. Prirodn. Soedin., 184 (1969).Google Scholar
  3. 3.
    V. I. Sheichenko and K. S. Rybalko, Khim. Prirodn. Soedin., 687 (1970).Google Scholar
  4. 4.
    J. L. Breton, B. G. Marrero, and A. G. Gonzales, Anales de Quimica,64, 1015 (1968).Google Scholar
  5. 5.
    A. G. Gonzales, B. G. Marrero, and J. L. Breton, Anales de Quimica,66, 799 (1970).Google Scholar
  6. 6.
    M. Karplus, J. Chem. Phys.,30, 11 (1959).CrossRefGoogle Scholar
  7. 7.
    M. Karplus, J. Amer. Chem. Soc.,85, 2870 (1963).CrossRefGoogle Scholar
  8. 8.
    Z. Samek, Abstracts of the Seventh International Symposium on the Chemistry of Natural Compounds [in Russian], Riga (1970), p. 708.Google Scholar
  9. 9.
    W. Herz, K. Aota, M. Holub, and Z. Samek, J. Org. Chem.,35, 2611 (1970).CrossRefGoogle Scholar
  10. 10.
    A. A. Bather-By, Advan. Magnetic Resonance,1, 195 (1965).CrossRefGoogle Scholar
  11. 11.
    R. C. Cookson, J. J. Frankel, J. Hudec, and T. A. Crabb, Tetrahedron Supp., No. 7, 355 (1966).CrossRefGoogle Scholar
  12. 12.
    F. V. Brutcher and W. J. Bauer, J. Amer. Chem. Soc.,84, 2236 (1962).CrossRefGoogle Scholar
  13. 13.
    T. Nambara, H. Hosoda, and S. Goya, Chem. and Pharmac. Bull.,16, No. 2, 374 (1968).CrossRefGoogle Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • V. I. Sheichenko
  • K. S. Rybalko

There are no affiliations available

Personalised recommendations