Advertisement

Chemistry of Natural Compounds

, Volume 8, Issue 1, pp 1–5 | Cite as

A new acid from the oil of the seeds of Sambucus nigra

  • É. I. Gigienova
  • A. U. Umarov
Article

Summary

A new keto hydroxy acid (I) C18H30O6 has been isolated from the fatty oil of the seeds ofSambucus nigra in an amount of 2% of the total fatty acids. A study of its chemical properties and spectral characteristics has shown that it is probably 11-hydroxy-9,15,16-trioxooctadeconoic acid, and that it consists of a keto-enol mixture containing about 30% of the two equiprobable tautomers (II and III); it has been given the name of caprifolonic acid.

Keywords

Methyl Oleate Azelaic Acid Glutaric Acid Chromium Trioxide Ethylene Succinate 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    É. I. Gigienova, A. U. Umarov, and A. L. Markman, Khim. Prirodn. Soedin.,5, 117 (1969).Google Scholar
  2. 2.
    É. I. Gigienova, A. U. Umarov, and A. L. Markman, Maslob.-Zhir. Prom.,9, 34 (1969).Google Scholar
  3. 3.
    Handbook on Methods of Investigation, Technical and Chemical Control, and the Accounting of Production in the Fats and Oils Industry [in Russian], Leningrad,1, Book 2 (1967), p. 1000.Google Scholar
  4. 4.
    Determination of the Structure of Organic Compounds by Physical and Chemical Methods [in Russian], Moscow,1, 53, 128 (1967);2, 525 (1967).Google Scholar
  5. 5.
    Houben-Weyl, Methoden der organischen Chemie [Russian translation], Moscow,2, 375–377, 436, 443, 455, 465, 469 (1967).Google Scholar
  6. 6.
    H. P. Kaufmann, Fette u. Seifen,53 (1951).Google Scholar
  7. 7.
    N. Bhacca and D. Williams, Applications of NMR Spectroscopy in Organic Chemistry, Holden-Day, San Francisco (1964).Google Scholar
  8. 8.
    S. D. Gusakova, É. I. Gigienova, A. U. Umarov, and A. L. Markman, Maslob.-Zhir. Prom.,10, 9 (1969).Google Scholar
  9. 9.
    L. J. Morris, R. T. Holmann, and K. Fontell, J. Lipid Res.,2, 68 (1961).Google Scholar
  10. 10.
    J. C. Hancock, G. O. Humphreys, and P. M. Meadow, Biochem. J.,113, 3, 30 (1969).CrossRefGoogle Scholar
  11. 11.
    H. J. Stan and J. Schormuller, J. Chrom.,43, 1, 103–109 (1969).CrossRefGoogle Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1974

Authors and Affiliations

  • É. I. Gigienova
  • A. U. Umarov

There are no affiliations available

Personalised recommendations