Conclusions
1. Xanthalin has been shown to have the structure of 2′, 2′-dimethyl-3′, 4′,-diangeloyloxy-3′, 4′-dihydropyrano-5′, 6′:6, 7-coumarin on the basis of the preparation of a number of derivatives and cleavage products.
2. The following products of the alkaline hydrolysis of xanthalin have been isolated and characterized for the first time: (±)-3′, 4′-dihydroxy-3′, 4′-dihydroxanthyletin (isokhellactone), C14H14O5, with mp 213–215° C and (−)-trans-3′-hydroxy-4′-methoxy-3′, 4′-dihydroxanthyletin (isomethylkhellactone, C15H16O5, with mp 136.5–138° C and [α] 20D −47.7 (ethanol).
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References
A. I. Sokolova, G. K. Nikonov, M. E. Perel'son, G. P. Syrova, and Yu. N. Sheinker, KhPS [Chemistry of Natural Compounds], 280, 1968.
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Khimiya Prirodnykh Soedinenii, Vol. 6, No. 1, pp. 14–19, 1970
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Sokolova, A.I., Nikonov, G.K. Structure of xanthalin. Chem Nat Compd 6, 12–15 (1970). https://doi.org/10.1007/BF00564147
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DOI: https://doi.org/10.1007/BF00564147