Conclusions
The pyrolisis of bucharaine and its acetonide derivative (II) forms the products of an anomalous, and their fusion with alkali, the products of the normal, Claisen rearrangement. Product (VII) is identical with bucharamine.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
K. Ubaidullaev, I. A. Bessonova, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 343 (1972).
Z. Sh. Faizutdinova, I. A. Bessonova, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 239 (1970).
Ya. V. Rashkes, Z. Sh. Faizutdinova, I. A. Bessonova, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 577 (1970).
A. V. Robertson, Aust. J. Chem.,16, 451 (1963).
B. D. Paul and P. K. Bose, Indian J. Chem.,7, 678 (1969).
E. A. Clarke and M. F. Grundon, J. Chem. Soc., 4190 (1964).
T. R. Chamberlain and M. F. Grundon, J. Chem. Soc. (C), 910 (1971).
Collection: Organic Reactions [Russian translation], Vol. 2, Moscow (1950), p. 22.
E. N. Marvell and D. R. Anderson, J. Org. Chem.,27, 1109 (1962).
Ya. V. Rashkes, I. A. Bessonova, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 336 (1972).
D. M. Razzakova, I. A. Bessonova, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 755 (1972).
Additional information
Order of the Red Banner of Labor Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Uzbek SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 358–364, May–June, 1974.
Rights and permissions
About this article
Cite this article
Bessonova, I.A., Rashkes, Y.V. & Yunusov, S.Y. Study of the Claisen rearrangement of bucharaine and its acetonide derivative. Chem Nat Compd 10, 359–363 (1974). https://doi.org/10.1007/BF00563893
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00563893