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Chemistry of Natural Compounds

, Volume 8, Issue 4, pp 515–521 | Cite as

Olivomycin and related antibiotics XXVI. The absolute configurations of olivin and of chromomycinone

  • Yu. A. Berlin
  • M. N. Kolosov
  • L. A. Piotrovich
Article
  • 15 Downloads

Summary

The stereochemical correlation of olivin with chromomycinone and the directed degradation of the first of them to di-O-methyl-D-tartaric acid (XXI) has been effected. As a result, it has been shown that olivin and chromomycinone both have the absolute configuration 2S,3R,1′S,3′S,4′R and possess the respective structures (Ia) and (Ib).

Keywords

Ethyl Acetate Absolute Configuration Methyl Stearate Ketol Hydroxy Ester 

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Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1974

Authors and Affiliations

  • Yu. A. Berlin
  • M. N. Kolosov
  • L. A. Piotrovich

There are no affiliations available

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