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Olivomycin and related antibiotics XXVI. The absolute configurations of olivin and of chromomycinone

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Summary

The stereochemical correlation of olivin with chromomycinone and the directed degradation of the first of them to di-O-methyl-D-tartaric acid (XXI) has been effected. As a result, it has been shown that olivin and chromomycinone both have the absolute configuration 2S,3R,1′S,3′S,4′R and possess the respective structures (Ia) and (Ib).

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Literature cited

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Authors
  1. Yu. A. Berlin
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  2. M. N. Kolosov
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  3. L. A. Piotrovich
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Additional information

For Communication XXV, see [1], and for a preliminary communication see [2].

M. M. Shemyakin Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 526–534, July–August, 1972.

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Berlin, Y.A., Kolosov, M.N. & Piotrovich, L.A. Olivomycin and related antibiotics XXVI. The absolute configurations of olivin and of chromomycinone. Chem Nat Compd 8, 515–521 (1972). https://doi.org/10.1007/BF00563684

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  • DOI: https://doi.org/10.1007/BF00563684

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