The structure of grilactone
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The structure of grilactone has been established. It corresponds to guai-1(2),13-dien-12,8-olide.
The permanganate oxidation of grilactone, isogrilactone, and dihydrogrilactone forms, together with the normal oxidation products, monooxides of the guaianolides containing a γ-oxide ring linking carbon atoms 1 and 7.
KeywordsLactone Hydroxy Derivative Monohydroxy Chromium Trioxide Permanganate Oxidation
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- 1.N. P. Kir'yalov, Zh. Obshch. Khim.,34, No. 11, 3831 (1964).Google Scholar