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Preparation of 10β-hydroperoxides of the pregnane series

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Summary

The synthesis of 10β-hydroperoxy-19-norpregn-4-ene-3,20-dione and its 16α, 17α-dimethyl derivative from the corresponding 10β-carboxylic acids has been effected. The influence of solvents and catalysts on the autooxidation of the acids has been studied.

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Literature cited

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Authors
  1. V. I. Bayunova
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  2. G. S. Grinenko
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Additional information

S. Ordzhonikidze All-Union Scientific-Research Institute of Pharmaceutical Chemicals. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 179–184, March–April, 1973.

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Bayunova, V.I., Grinenko, G.S. Preparation of 10β-hydroperoxides of the pregnane series. Chem Nat Compd 9, 174–178 (1973). https://doi.org/10.1007/BF00563338

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  • DOI: https://doi.org/10.1007/BF00563338

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