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Aziridinyl ketones and their hetero analogs 4. Acidolysis of 1, 1a-dihydroazirino [1,2-a] quinoxalines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The isomerization of 1,2-diaryl-1, 1a-dihydroazirino[1,2-a]quinozalines into 3-aryl-2-benzylquinoxalines under the action of acids is considered. The structures of the compounds synthesized have been confirmed by IR and PMR spectroscopy. It has been shown that the center of protonation in the azirinoquinoxalines and the model 1,2-dihydro-2,3-diphenylquinoxaline is the nitrogen atom of the azomethine group.

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Authors and Affiliations

  1. A. M. Gorkii Kharkov State University, Kharkov

    V. D. Orlov, F. G. Yaremenko, N. N. Kolos, N. S. Pivnenko & V. F. Lavrushin

Authors
  1. V. D. Orlov
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  2. F. G. Yaremenko
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  3. N. N. Kolos
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  4. N. S. Pivnenko
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  5. V. F. Lavrushin
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Additional information

For communication 3, see [2].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 544–549, April, 1980.

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Orlov, V.D., Yaremenko, F.G., Kolos, N.N. et al. Aziridinyl ketones and their hetero analogs 4. Acidolysis of 1, 1a-dihydroazirino [1,2-a] quinoxalines. Chem Heterocycl Compd 16, 424–428 (1980). https://doi.org/10.1007/BF00552787

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  • DOI: https://doi.org/10.1007/BF00552787

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