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Mass-spectrometric identification of certain 2-(ɛ-benzoylaminocaproylamino)benzophenones and their di- and tetraazamacrocyclic cyclization products

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Dissociation occurring during mass-spectrometric measurements of 2-(benzoylaminocaproylamino)benzophenones substituted in the benzene ring and also of 11- and 22-membered di- and tetraazaheterocycles obtained by their intra- and intermolecular cyclization proceeds preferentially at the amide C-N bonds, partially with the transfer of a hydrogen atom to the amino group. The size and character of the heterocycle can be established by analyzing the intensities of the characteristic ions.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, 117234, Moscow

    P. B. Terent'ev, Hasan Sami Ajami, Yu. G. Bundel', L. K. Kolmagortseva, S. A. Andronati & A. V. Bogatskii

  2. Physicochemical Institute, Academy of Sciences of the Ukrainian SSR, 270080, Odessa

    P. B. Terent'ev, Hasan Sami Ajami, Yu. G. Bundel', L. K. Kolmagortseva, S. A. Andronati & A. V. Bogatskii

Authors
  1. P. B. Terent'ev
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  2. Hasan Sami Ajami
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  3. Yu. G. Bundel'
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  4. L. K. Kolmagortseva
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  5. S. A. Andronati
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  6. A. V. Bogatskii
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 528–532, April, 1987.

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Terent'ev, P.B., Ajami, H.S., Bundel', Y.G. et al. Mass-spectrometric identification of certain 2-(ɛ-benzoylaminocaproylamino)benzophenones and their di- and tetraazamacrocyclic cyclization products. Chem Heterocycl Compd 23, 440–443 (1987). https://doi.org/10.1007/BF00546743

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  • DOI: https://doi.org/10.1007/BF00546743

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