Abstract
A study was carried out on the reaction of 5-nitro and 5-nitromethoxypyrimidines with the acetylacetone carbanion. Benzene and pyridine derivatives are formed as a result of recyclization. The direction of the reaction depends on the position of the substituents in the pyrimidine ring and the nature of the bases.
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Communication 6, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 508–512, April, 1987.
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Remennikov, G.Y., Kurilenko, L.K., Boldyrev, I.V. et al. Pyrimidine sigma-complexes. 7. The recyclization of 5-nitropyrimidine and its methoxy derivatives upon reaction with the acetylacetone carbanion. Chem Heterocycl Compd 23, 422–425 (1987). https://doi.org/10.1007/BF00546740
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DOI: https://doi.org/10.1007/BF00546740