Abstract
A study was made of the kinetics of the reduction of eleven 5-nitro-2-substituted thiophenes to acetylaminothiophenes using Raney nickel in acetic anhydride. The dependence of the rate of the reaction both on the induction effect of the substituents and on the ratio of the adsorption constants of the reaction products and substrate was determined.
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Literature Cited
G. N. Freidlin, A. A. Glushkova, and K. A. Solon, Khim. Geterosikl. Soedin., No. 2, 167 (1982).
Ya. L. Gol'dfarb, B. P. Fabrichnyi, and E. A. Krasnyanskaya, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 1825 (1962).
Ya. L. Gol'dfarb, M. M. Polonskaya, B. P. Fabrichnyi, and I. F. Shalavina, Dokl. Akad. Nauk, 126, 86 (1956).
Ya. L. Gol'dfarb, B. P. Fabrichnyi, and I. F. Shalavina, Khim. Geterosikl. Soedin., No. 10, 1223 (1982).
R. Guilard, I. Nonciaux, E. Laviron, and P. Fournari, J. Heterocycl. Chem., 12, 191 (1975).
B. P. Fabrichnyi, S. E. Zurabyan, I. F. Shalavina, and Ya. L. Gol'dfarb, Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 2102 (1967).
G. S. Bashkirova and S. L. Kiperman, Kinet. Katal., 11, 631 (1970).
J. Jungers and L. Sajus, Kinetic Methods for the Investigation of Chemical Processes [Russian translation], Khimiya, Leningrad (1972), p. 151.
G. N. Freidlin, A. A. Glushkova, and K. A. Solon, Zh. Anal. Khim., 34, 381 (1979).
B. P. Fabrichnyi, S. M. Kostrova, G. P. Gromova, and Ya. L. Gol'dfarb, Khim. Geterosikl. Soedin., No. 11, 1483 (1973).
A. E. Lipkin, Zh. Org. Khim., 33, 169 (1963).
I. M. Sosonkin, G. N. Strogov, T. K. Ponomareva, A. N. Domarev, A. A. Glushkova, and G. N. Freidlin, Khim. Geterosikl. Soedin., No. 2, 195 (1981).
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Translated from Khimiya Geterosiklicheskikh Soedinenii, No. 4, pp. 455–459, April, 1987.
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Glushkova, A.A., Morgunova, L.M., Freidlin, G.N. et al. Reductive acylation of 5-nitro-2R-thiophenes. Chem Heterocycl Compd 23, 380–384 (1987). https://doi.org/10.1007/BF00546728
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DOI: https://doi.org/10.1007/BF00546728