Skip to main content
Log in

Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

Journal of Materials Science Aims and scope Submit manuscript

Abstract

The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO 3 units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. F. Lambson, G. A. Saunders, B. Bridge and R. A. El-Mallawany, J. Non-Cryst. Solids 69 (1984) 117.

    Article  CAS  Google Scholar 

  2. N. Mochida and K. Takahashi, Yogyo-Kyokai-Shi 86 (1978) 317.

    Article  Google Scholar 

  3. T. Yoko, K. Kamiya, K. Tanaka, H. Yamada and S. Sakka, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 97 (1989) 289.

    Article  CAS  Google Scholar 

  4. M. Arnaudov, V. Dimitrov, Y. Dimitriev and L. Markova, Mater. Res. Bull. 17 (1982) 1121.

    Article  CAS  Google Scholar 

  5. M. Imaoka and T. Yamasaki, Yogyo-Kyokai-Shi 76 (1968) 160.

    Article  CAS  Google Scholar 

  6. H. Nasu, O. Matsusita, K. Kamiya, H. Kobayashi and K. Kubodera, J. Non-Cryst. Solids 124 (1990) 275.

    Article  CAS  Google Scholar 

  7. J. E. Huheey, “Inorganic chemistry”, 3rd Edn (Harper and Row, New York, 1983) Ch. 5.

    Google Scholar 

  8. K. Suzuki, J. Non-Cryst. Solids 95/96 (1987) 15.

    Article  Google Scholar 

  9. Y. Dimitriev, V. Dimitrov and M. Arnaudov, J. Mater. Sci. 18 (1983) 1353.

    Article  CAS  Google Scholar 

  10. M. Dimitrova-Pankova, Y. Dimitrov, M. Arnaudov and V. Dimitrov, Phys. Chem. Glasses 30 (1989) 260.

    CAS  Google Scholar 

  11. R. Göring, H. Bürger, H. Nass and B. Schnabel, Physica Status Solidi (a) 68 (1981) k29.

    Article  Google Scholar 

  12. Y. Kaneko, H. Nakamura, M. Yamane, K. Mizoguchi and Y. Suginohara, Yogyo-Kyokai-Shi 91 (1983) 321.

    Article  CAS  Google Scholar 

  13. W. L. Konijnendijk and J. M. Stevels, J. Non-Cryst. Solids 18 (1975) 30.

    Article  Google Scholar 

  14. A. Bhargava, R. L. Snyder and R. A. Condrate, Sr. Mater. Res. Bull. 22 (1987) 1603.

    Article  CAS  Google Scholar 

  15. T. Sekiya, N. Mochida, J. Ohtsuka and M. Tonokawa, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 97 (1989) 1435.

    Article  CAS  Google Scholar 

  16. O. Lindqvist, W. Mark and J. Moret, Acta Crystallogr. B31 (1975) 1255.

    Article  CAS  Google Scholar 

  17. R. Masse, J. C. Guitel and I. Tordjman, Mater. Res. Bull. 15 (1980) 431.

    Article  CAS  Google Scholar 

  18. H. Meyer, Z. Kristallogr. 124 (1967) 228.

    Article  Google Scholar 

  19. O. Lindqvist, Acta Chem. Scand. 22 (1968) 977.

    Article  CAS  Google Scholar 

  20. B. Buss and B. Krebs, Inorg. Chem. 10 (1971) 2795.

    Article  CAS  Google Scholar 

  21. B. Mysen, W. Larry, W. Finger, O. Virgo and F. A. Seifert, Amer. Mineral. 67 (1982) 686.

    CAS  Google Scholar 

  22. G. Menorah and J. Gary, Acta Crystallogr. B27 (1972) 602.

    Google Scholar 

  23. N. Mochida, T. Sekiya, J. Ohtsuka and Tonokawa, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 96 (1988) 973.

    Article  CAS  Google Scholar 

  24. J. E. Huheey, “Inorganic chemistry”, 3rd Edn (Harper and Row, New York, 1983) Ch. 3.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rong, Q.J., Osaka, A., Nanba, T. et al. Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides. J Mater Sci 27, 3793–3798 (1992). https://doi.org/10.1007/BF00545458

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00545458

Keywords

Navigation