Abstract
The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO −3 units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.
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E. F. Lambson, G. A. Saunders, B. Bridge and R. A. El-Mallawany, J. Non-Cryst. Solids 69 (1984) 117.
N. Mochida and K. Takahashi, Yogyo-Kyokai-Shi 86 (1978) 317.
T. Yoko, K. Kamiya, K. Tanaka, H. Yamada and S. Sakka, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 97 (1989) 289.
M. Arnaudov, V. Dimitrov, Y. Dimitriev and L. Markova, Mater. Res. Bull. 17 (1982) 1121.
M. Imaoka and T. Yamasaki, Yogyo-Kyokai-Shi 76 (1968) 160.
H. Nasu, O. Matsusita, K. Kamiya, H. Kobayashi and K. Kubodera, J. Non-Cryst. Solids 124 (1990) 275.
J. E. Huheey, “Inorganic chemistry”, 3rd Edn (Harper and Row, New York, 1983) Ch. 5.
K. Suzuki, J. Non-Cryst. Solids 95/96 (1987) 15.
Y. Dimitriev, V. Dimitrov and M. Arnaudov, J. Mater. Sci. 18 (1983) 1353.
M. Dimitrova-Pankova, Y. Dimitrov, M. Arnaudov and V. Dimitrov, Phys. Chem. Glasses 30 (1989) 260.
R. Göring, H. Bürger, H. Nass and B. Schnabel, Physica Status Solidi (a) 68 (1981) k29.
Y. Kaneko, H. Nakamura, M. Yamane, K. Mizoguchi and Y. Suginohara, Yogyo-Kyokai-Shi 91 (1983) 321.
W. L. Konijnendijk and J. M. Stevels, J. Non-Cryst. Solids 18 (1975) 30.
A. Bhargava, R. L. Snyder and R. A. Condrate, Sr. Mater. Res. Bull. 22 (1987) 1603.
T. Sekiya, N. Mochida, J. Ohtsuka and M. Tonokawa, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 97 (1989) 1435.
O. Lindqvist, W. Mark and J. Moret, Acta Crystallogr. B31 (1975) 1255.
R. Masse, J. C. Guitel and I. Tordjman, Mater. Res. Bull. 15 (1980) 431.
H. Meyer, Z. Kristallogr. 124 (1967) 228.
O. Lindqvist, Acta Chem. Scand. 22 (1968) 977.
B. Buss and B. Krebs, Inorg. Chem. 10 (1971) 2795.
B. Mysen, W. Larry, W. Finger, O. Virgo and F. A. Seifert, Amer. Mineral. 67 (1982) 686.
G. Menorah and J. Gary, Acta Crystallogr. B27 (1972) 602.
N. Mochida, T. Sekiya, J. Ohtsuka and Tonokawa, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 96 (1988) 973.
J. E. Huheey, “Inorganic chemistry”, 3rd Edn (Harper and Row, New York, 1983) Ch. 3.
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Rong, Q.J., Osaka, A., Nanba, T. et al. Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides. J Mater Sci 27, 3793–3798 (1992). https://doi.org/10.1007/BF00545458
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DOI: https://doi.org/10.1007/BF00545458