Abstract
Different sol-gel methods for the preparation of ZrO2 were investigated. Depending on the chemical composition of the initial solutions, various results such as gel-precipitation, the formation of stable sols or amorphous gels were obtained. Sols prepared by different methods are composed of different structural units and exhibit quite different rheological behaviour such as shear thickening, Newtonian flow, shear thinning and thixotropic flow. By variation of the chemical composition of the sol, an optimized rheological behaviour can be achieved for a given purpose.
References
H. Dislich and P. Hinz, J. Non-Cryst. Solids 48 (1982) 11.
J. C. Debsikdar, ibid. 91 (1987) 262.
F. Bel Wady, R. Sempere and J. Phalippou, ibid. 82 (1986) 417.
G. W. Scherer, Yogyo Kyokai-Shi 95 (1987) 21.
K. D. Keefer, in “Better Ceramics Through Chemistry”, edited by C. J. Brinker, D. E. Clark and D. R. Ulrich, Materials Research Society Symposium Proceedings, Vol. 32 (Elsevier, New York, 1984) p. 15.
J. C. Debsikdar, J. Non-Cryst. Solids 86 (1986) 231.
C. Guizard, N. Cygankiewicz, A. Larbot and L. Cot, ibid. 82 (1986) 86.
D. Kundu and D. Ganguli, J. Mater. Sci. Lett. 5 (1986) 293.
K. Kamiya, T. Yoko, K. Tanaka and H. Itoh, Yogyo Kyokai-Shi 95 (1987) 1157.
P. Kundu, D. Pal and S. Sen, J. Mater. Sci. 23 (1988) 1539.
B. Fegley Jr, P. White and H. K. Bowen, Amer. Ceram. Soc. Bull. 64 (1985) 1115.
K. S. Mazdiyasni, C. T. Lynch and J. S. Smith, J. Amer. Ceram. Soc. 50 (1967) 532.
M. K. Dongare and A. P. B. Sinha, J. Mater. Sci. 19 (1984) 49.
T. Ogihara, N. Mizutani and M. Kato, Ceram. Int. 13 (1987) 35.
K. Yamada, T. Y. Chow, T. Horihata and M. Nagata, J. Non-Cryst. Solids 100 (1988) 316.
T. Kokubo, Y. Teranishi and T. Maki, ibid. 56 (1983) 411.
P. Singh and S. K. Date, J. Mater. Sci. Lett. 6 (1987) 621.
T. Y. Tseng, C. C. Lin and J. T. Liaw, J. Mater. Sci. 22 (1987) 965.
R. J. Card, Adv. Ceram. Mater. 3 (1988) 29.
B. H. Davis, J. Amer. Ceram. Soc. 67 (1984) C168.
M.-I. Osendi, J. S. Moya, C. J. Serna and J. Soria, ibid. 68 (1985) 135.
D. B. Marshall, F. F. Lange and P. D. Morgan, ibid. 70 (1987) C187.
E. Leroy, C. Robin-Brosse and J. P. Torre, in “Ultrastructure Processing of Ceramics, Glasses and Composites”, edited by L. L. Hench and D. R. Ulrich (Wiley, New York, 1984) p. 219.
M. E. Khavari, F. F. Lange, P. Smith and D. B. Marshall, in “Better Ceramics Through Chemistry III”, edited by C. J. Brinker, D. E. Clark and D. R. Ulrich, Materials Research Society Symposium Proceedings, Vol. 121 (Elsevier, New York, 1989) p. 617.
S. Doeuff, M. Henry, C. Sanchez and J. Livage, J. Non-Cryst. Solids 89 (1987) 206.
J. Livage, in “Better Ceramics Through Chemistry II”, edited by C. J. Brinker, D. E. Clark and D. R. Ulrich, Materials Research Society Symposium Proceedings, Vol. 73 (Elsevier, New York, 1986) p. 717.
S. Sakka and K. Kamiya, J. Non-Cryst. Solids 48 (1982) 31.
C. Sanchez, J. Livage, M. Henry and F. Babonneau, ibid. 100 (1985) 65.
K. Nakamoto, “Infrared and Raman Spectra of Inorganic and Coordination Compounds”, 3rd Edn (Wiley, New York, 1978) pp. 227, 380.
K. H. Thiele and M. Panse, Z. Anorg. Allg. Chem. 441 (1978) 23.
H. Kozuka, H. Kuroki and S. Sakka, J. Non-Cryst. Solids 100 (1988) 226.
Idem, ibid. 101 (1988) 120.
S. Sakka and H. Kozuka, ibid. 100 (1988) 142.
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Wolf, C., Rüssel, C. Sol-gel formation of zirconia: preparation, structure and rheology of sols. J Mater Sci 27, 3749–3755 (1992). https://doi.org/10.1007/BF00545451
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DOI: https://doi.org/10.1007/BF00545451