Hydrotalcite-like compounds obtained by anion exchange reactions

Abstract

The synthesis of nickel aluminium hydroxypicrate, [Ni3Al(OH)8] (C6O7N3H2)·nH 2O, and lithium aluminium hydroxypicrate, [Al2Li(OH)6] (C6O7N3H2)·nH 2O by anion exchange is described. Picric acid and the corresponding hydroxycarbonates were used as starting materials. The new compounds were characterized by chemical analyses, electron microscopy, infrared spectroscopy and X-ray diffraction. The results obtained indicate that both are hydrotalcite-like compounds where the picrate anion lies between the basic layers. The thermal decomposition of the compounds was studied by differential thermal and thermogravimetric analysis.

This is a preview of subscription content, access via your institution.

References

  1. 1.

    R. Allmann, Acta Crystallogr. B24 (1968) 972.

    Article  Google Scholar 

  2. 2.

    H. F. W. Taylor, Mineral. Mag. 39 (1973) 377.

    CAS  Article  Google Scholar 

  3. 3.

    S. Miyata, Clays & Clay Miner. 23 (1975) 369.

    CAS  Article  Google Scholar 

  4. 4.

    C. J. Serna, J. L. Rendon and J. E. Iglesias, ibid. 30 (1982) 180.

    CAS  Article  Google Scholar 

  5. 5.

    M. J. Hernandez, M. A. Ulibarri, J. L. Rendon and C. J. Serna, Phys. Chem. Miner. 12 (1985) 34.

    Google Scholar 

  6. 6.

    I. Sissoko, E. T. Iyagba, R. Sahai and P. Biloen, J. Solid State Chem. 60 (1985) 283.

    CAS  Article  Google Scholar 

  7. 7.

    D. L. Bish, Bull. Mineral. 103 (1980) 170.

    CAS  Google Scholar 

  8. 8.

    S. Miyata, Clays & Clay Miner. 31 (1983) 305.

    CAS  Article  Google Scholar 

  9. 9.

    M. A. Ulibarri, M. J. Hernandez, J. Cornejo and C. J. Serna, Mater. Chem. Phys. 14 (1986) 569.

    CAS  Article  Google Scholar 

  10. 10.

    T. Kown, G. A. Tsigdinos and T. J. Pinnavaia, J. Amer. Chem. Soc. 110 (1988) 3653.

    Article  Google Scholar 

  11. 11.

    E. Suzuki, S. Idemura and Y. Ono, Clays & Clay Miner. 37 (1989) 173.

    CAS  Article  Google Scholar 

  12. 12.

    M. J. Hernandez, M. A. Ulibarri, J. L. Rendon and C. J. Serna, Thermochim. Acta 81 (1984) 311.

    CAS  Article  Google Scholar 

  13. 13.

    M. A. Ulibarri, J. Cornejo and M. J. Hernandez, J. Mater. Sci. 22 (1987) 1168.

    CAS  Article  Google Scholar 

  14. 14.

    A. Schutz and P. Biloen, J. Solid State Chem. 68 (1987) 360.

    CAS  Article  Google Scholar 

  15. 15.

    E. Pretsch, T. Clerc, J. Seibl and W. Simon, “Tablas para la elucidación estructural de compuestos orgánicos por métodos espectroscópicos” (Alhambra, Madrid, 1980).

    Google Scholar 

  16. 16.

    M. J. Hernandez, minor thesis, Cordoba, Spain, 1982.

  17. 17.

    M. A. Ulibarri, J. M. Luque and J. Cornejo, Mater. Chem. Phys. 25 (1990) 81.

    CAS  Article  Google Scholar 

  18. 18.

    G. Mascolo, Thermochim. Acta 102 (1986) 67.

    CAS  Article  Google Scholar 

  19. 19.

    K. R. Poeppelmeier and S.-J. Hwu, Inorg. Chem. 26 (1987) 3297.

    CAS  Article  Google Scholar 

Download references

Author information

Affiliations

Authors

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Ulibarri, M.A., Hernandez, M.J. & Cornejo, J. Hydrotalcite-like compounds obtained by anion exchange reactions. J Mater Sci 26, 1512–1516 (1991). https://doi.org/10.1007/BF00544660

Download citation

Keywords

  • Polymer
  • Electron Microscopy
  • Nickel
  • Lithium
  • Thermal Decomposition