Skip to main content
Log in

Comparative study of spinodal decomposition in symmetric and asymmetric Cu-Ni-Cr alloys

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Spinodal decomposition in three alloys of nominal compositions 71Cu-27Ni-2Cr, 45Cu-45Ni-10Cr and 33Cu-52Ni-15Cr were studied by X-ray diffraction technique and transmission electron microscopy. It was found that the first and third alloys are asymmetric in nature while the second is symmetric. The symmetric alloy was found to decompose faster than the asymmetric ones. The asymmetry of the side bands was found to be related to the proportion of phases in the alloy. Electron microscopic studies revealed that during coarsening the major phase increases its connectivity by isolating the minor phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. L. Meijering, G. W. Rathenau, M. G. Van Der Steeg and P. B. Braun, J. Inst. Met. 84 (1950–56) 118.

    Google Scholar 

  2. J. Manenc, Acta Metall. 6 (1958) 145.

    Article  Google Scholar 

  3. C. K. Wu and G. Thomas, Met. Trans. 8A (1977) 1911.

    Article  CAS  Google Scholar 

  4. A. Chou, A. Dutta, G. H. Meier and W. A. Soffa, J. Mater. Sci. 13 (1978) 541.

    Article  CAS  Google Scholar 

  5. D. Bower, G. W. Lorimer, I. Saunderson and P. Wilkes, Met. Tech. 7 (1980) 120.

    Article  CAS  Google Scholar 

  6. R. Knights and P. Wilkes, Met. Trans. 4 (1973) 2389.

    Article  CAS  Google Scholar 

  7. R. I. Saunderson, P. Wilkes and G. W. Lorimer, Acta Metall. 26 (1978) 1357.

    Article  CAS  Google Scholar 

  8. P. Prasad Rao, B. K. Agrawal and A. M. Rao, J. Mater. Sci. 21 (1986) 3759.

    Article  CAS  Google Scholar 

  9. W. A. Rachinger, J. Sci. Instrum. 25 (1948) 254.

    Article  Google Scholar 

  10. W. B. Pearson, “Handbook of lattice spacings and structures of metals” (Pergamon, New York, 1958) p. 592.

    Google Scholar 

  11. V. Daniel and H. Lipson, Proc. R. Soc. A181 (1943) 368.

    Google Scholar 

  12. M. Hillert, Acta Metall. 9 (1961) 525.

    Article  CAS  Google Scholar 

  13. J. W. Cahn, Trans. Met. Soc. AIME 242 (1968) 166.

    CAS  Google Scholar 

  14. R. J. Livak and G. Thomas, Acta Metall. 19 (1971) 497.

    Article  CAS  Google Scholar 

  15. D. E. Laughlin and J. W. Cahn, ibid. 23 (1975) 329.

    Article  CAS  Google Scholar 

  16. T. Miyazaki, S. Takagishi, H. Mori and T. Kozakai, ibid. 28 (1980) 1143.

    Article  CAS  Google Scholar 

  17. J. E. Hilliard, Spinodal Decomposition, in “Phase Transformations” edited by H. I. Aaronson (American Society for Metals, Metals Park, OH, 1970) pp. 497–560.

    Google Scholar 

  18. R. W. Carpenter, Acta Metall. 15 (1967) 1567.

    Article  CAS  Google Scholar 

  19. H. E. Cook and J. E. Hilliard, J. Appl. Phys. 40 (1969) 2191.

    Article  CAS  Google Scholar 

  20. T. Miyazaki, T. Shinozawa, H. Murayama and H. Mori, Trans. Jpn. Inst. Met. 17 (1976) 181.

    Article  CAS  Google Scholar 

  21. R. Hultgren, P. D. Desai, D. T. Hawkins, M. Gleiser and K. K. Kelly, “Selected values of the thermodynamic properties of binary alloys” (American Society for Metals, Metals Park, OH, 1973) p. 763.

    Google Scholar 

  22. C. J. Smithels, “Metals Reference Book” (Butterworths, London, 1976).

    Google Scholar 

  23. I. M. Lifshitz and V. V. Slyozov, J. Phys. Chem. Solids 19 (1961) 35.

    Article  Google Scholar 

  24. C. Wagner, Z. Elektrochem. 65 (1961) 581.

    CAS  Google Scholar 

  25. V. Daniel and H. Lipson, Proc. R. Soc. 182 (1944) 378.

    Article  CAS  Google Scholar 

  26. M. E. Hargreaves, Acta Crystallogr. 4 (1951) 301.

    Article  CAS  Google Scholar 

  27. T. J. Tiedema, J. Bouman and W. G. Burgers, Acta Metall. 5 (1957) 310.

    Article  CAS  Google Scholar 

  28. A. G. Katchaturyan, Phys. Status. Solidi 35 (1969) 19.

    Google Scholar 

  29. E. P. Butler and G. Thomas, Acta Metall. 18 (1970) 347.

    Article  CAS  Google Scholar 

  30. G. de Vos, J. Appl. Phys. 37 (1966) 1100.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rao, P.P., Agrawal, B.K. & Rao, A.M. Comparative study of spinodal decomposition in symmetric and asymmetric Cu-Ni-Cr alloys. J Mater Sci 26, 1485–1496 (1991). https://doi.org/10.1007/BF00544657

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00544657

Keywords

Navigation