Skip to main content
Log in

Hydrogenation process of Nd-Dy-Fe-B alloy

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The influence of the alloy granulation grade, temperature and surface oxidation on the kinetics and the course of the fracture processes during the hydrogenation of Nd16−xDyxFe76B8 (x=0–3) alloy was studied. The average particle sizes of the alloy were 1 mm, 5 mm and 3 cm and the temperature range between 20 and 200 °C. Pre-oxidation times of the alloy were 0, 5, 10, 20, 30, 1 20 and 1200 min. No influence of the alloy composition on the kinetics and fracture processes during the hydrogenation was observed. An influence of the granulation grade of the alloy particles on the reaction rate was established and an influence of increasing temperature on the shortening of the incubation period was observed. It was also shown that the incubation time is influenced by surface oxidation. A tentative model of the hydrogenation-decrepitation process is suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Sagawa, S. Fujimura, N. Togawa, H. Yamamoto and Y. Matsuura, J. Appl. Phys. 55 (1984) 2083.

    Article  CAS  Google Scholar 

  2. I. R. Harris, C. Noble and T. Bailey, J. Less-Common Metals 106 (1985) L1.

    Article  CAS  Google Scholar 

  3. I. R. Harris, ibid. 131 (1987) 245.

    Article  CAS  Google Scholar 

  4. I. R. Harris, P. J. McGuiness, D. G. R. Jones and J. S. Abell, Physica Scripta T19 (1987) 435.

    Article  Google Scholar 

  5. I. S. Moosa and J. Nutting, J. Less-Common Metals 144 (1988) 221.

    Article  CAS  Google Scholar 

  6. U. D. Schulz, W. E. Krönert and H. Nagel, in Proceedings of 9th International Workshop on Rare-Earth Magnets and their Application, Bad Soden, FRG (Deutsche Physikalische Geselschaft e. V., Bad Honef 1, 1987) p. 267.

    Google Scholar 

  7. P. J. McGuiness and I. R. Harris, J. Appl. Phys. 64 (1988) 5308.

    Article  CAS  Google Scholar 

  8. P. J. McGuiness, I. R. Harris, E. Rozendal, J. Ormerod and M. Ward, J. Mater. Sci. 21 (1986) 4107.

    Article  CAS  Google Scholar 

  9. E. Fromm and H. Uchida, J. Less-Common Metals 131 (1987) 1.

    Article  CAS  Google Scholar 

  10. L. Schlapbach, ibid. 111 (1985) 291.

    Article  Google Scholar 

  11. A. Efron, Y. Lifshitz, I. Lewkowicz and M. H. Mintz, ibid. 153 (1989) 23.

    Article  CAS  Google Scholar 

  12. B. Rupp, A. Resnik, D. Shaltiel and P. Rogl, J. Mater. Sci. 23 (1988) 2133.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Saje, B., Holc, J. & Beseničar, S. Hydrogenation process of Nd-Dy-Fe-B alloy. J Mater Sci 27, 2682–2686 (1992). https://doi.org/10.1007/BF00540690

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00540690

Keywords

Navigation