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Porphyrins. 10. New data on the polyformylation of metal complexes of octaethylporphyrin

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It is shown that α-chloro-γ-formyloctaethylporphyrin and porphyrins that contain a cyclopentane ring are formed along with monoformyloctaethylporphyrin and α,γ-diformyloctaethylporphyrin in the Vilsmeier formylation of the Co complex of octaethylporphyrin. Two crystalline modifications of the Zn complex of octaethylporphyrin were obtained, and their UV and IR spectra were studied.

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Literature cited

  1. G. V. Ponomarev, G. V. Kirillova, G. B. Maravin, T. A. Babushkina, and V. P. Suboch, Khim. Geterotsikl. Soedin., No. 6, 767 (1979).

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  2. E. Watanabe, S. Nishimura, H. Ogoshi, and Z. Yoshida, Tetrahedron, 31, 1385 (1975).

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  3. G. V. Ponomarev and A. N. Sidorov, Khim. Geterotsikl. Soedin., No. 7, 919 (1977).

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Authors and Affiliations

  1. Institute of Biophysics, Ministry of Public Health of the USSR, 123182, Moscow

    G. V. Ponomarev, G. V. Kirillova, G. B. Maravin, T. A. Babushkina & V. P. Suboch

Authors
  1. G. V. Ponomarev
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  2. G. V. Kirillova
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  3. G. B. Maravin
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  4. T. A. Babushkina
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  5. V. P. Suboch
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Additional information

See [1] for communication 9.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 776–779, June, 1979.

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Ponomarev, G.V., Kirillova, G.V., Maravin, G.B. et al. Porphyrins. 10. New data on the polyformylation of metal complexes of octaethylporphyrin. Chem Heterocycl Compd 15, 630–633 (1979). https://doi.org/10.1007/BF00539497

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  • DOI: https://doi.org/10.1007/BF00539497

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