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Synthesis and properties of derivatives of sym-triazines. 11. Synthesis of 2-amino-sym-triazines containing alkyl radicals

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-Amino-4,6-dialkyl-sym-triazenes were synthesized by the condensation of aliphatic nitriles with guanidine. 2-Amino-4-alkyl-6-substituted sym-triazines were prepared by the reaction of N-acylguanidines with nitriles or imino esters. Aminotriazines of this type are also formed in the condensation of N-imidoylguanidines with esters.

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References

  1. V. I. Kelarev, A. S. Remizov, R. A. Karakhanov, Yu. N. Polivin, and D. Oietauo, Khim. Geterotsikl. Soedin., No. 10, 1312 (1992).

    Google Scholar 

  2. V. I. Kelarev, Dibi Ammar, and A. F. Lunin, Khim. Geterotsikl. Soedin., No. 11, 1557 (1985).

    Google Scholar 

  3. V. I. Kelarev, Dibi Ammar, A. F. Lunin, and O. V. Malova, Zh. Org. Khim., 21, 1306 (1985).

    Google Scholar 

  4. V. I. Kelarev, R. A. Karakhanov, V. I. Zav'yalov, Dibi Ammar, A. N. Golovin, E. A. Lisitsyn, and M. Bellul, Zh. Org. Khim., 24, 1100 (1988).

    Google Scholar 

  5. H. Kabbe, K. Eiter, and F. Moelle, German Patent No. 1,212,547; Chem. Abstr., 64, 15900 (1966).

    Google Scholar 

  6. D. Alsofrom, H. Grossberg, and H. Sheffer, J. Heterocycl. Chem., 14, No. 4, 917 (1976).

    Google Scholar 

  7. V. I. Kelarev, R. A. Karakhanov, M. Bellul, R. A. Ushakova, and A. I. Mikaya, Khim. Geterotsikl. Soedin., No. 5, 674 (1988).

    Google Scholar 

  8. R. B. Russell, G. H. Hitchings, and B. H. Chase, J. Am. Chem. Soc., 74, No. 21, 5403 (1952).

    Google Scholar 

  9. V. I. Kelarev, R. A. Karakhanov, A. S. Kokosova, and G. D. Gankin, Khim. Geterotsikl. Soedin., No. 9, 1250 (1992).

    Google Scholar 

  10. H. Nagasaka, E. Joshikawa, and K. Odo, J. Syn. Org. Chem. Jpn., 25, 1048 (1967).

    Google Scholar 

  11. A. I. Finkel'shtein and E. N. Boitsov, Usp. Khim., 31, 1496 (1962).

    Google Scholar 

  12. A. R. Katritskii (ed.), Physical Methods in the Chemistry of Heterocyclic Compounds [in Russian], Khimiya, Moscow-Leningrad (1966), p. 594.

    Google Scholar 

  13. A. I. Finkel'shtein, Opt. Spektrosk., 5, 264 (1958).

    Google Scholar 

  14. P. N. Preston, P. W. Steedmann, M. H. Palmer, S. M. Mackenzie, and M. F. Stevens, Org. Mass Spectrom., 3, No. 7, 863 (1970).

    Google Scholar 

  15. R. Johnson, Handbook of Mass Spectrometry for Organic Chemists [Russian translation], Mir, Moscow (1975).

    Google Scholar 

  16. Q. H. Porter and J. Balders, Mass Spectrometry of Heterocyclic Compounds, Wiley-Interscience, New York (1971), p. 376.

    Google Scholar 

  17. Beilstein, Vol. 3, p. 75 (1932).

  18. W. Traube, Chem. Ber., 43, No. 8, 3590 (1910).

    Google Scholar 

  19. A. A. Smolyarchuk, A. P. Kobernik, N. I. Ivanova, I. M. Skvortsov, and Yu. V. Aleksashin, Khim.-farm. Zh., 10, No. 7, 72 (1976).

    Google Scholar 

  20. A. M. Drozdov and E. N. Bekhli, Zh. Org. Khim., 14, No. 2, 289 (1944).

    Google Scholar 

  21. H. Watanabe, Y. Kikugawa, and S. Yamada, Chem. Pharm. Bull., 21, No. 3, 465 (1973).

    Google Scholar 

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For Communication 10, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1271–1276, September, 1993.

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Kelarev, V.I., Karakhanov, R.A., Polivin, Y.N. et al. Synthesis and properties of derivatives of sym-triazines. 11. Synthesis of 2-amino-sym-triazines containing alkyl radicals. Chem Heterocycl Compd 29, 1087–1092 (1993). https://doi.org/10.1007/BF00534397

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  • DOI: https://doi.org/10.1007/BF00534397

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