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Chemistry of Heterocyclic Compounds

, Volume 29, Issue 8, pp 932–937 | Cite as

Saturated nitrogen-containing heterocycles. 16. Catalytic synthesis of N-arylperhydroacridines

  • T. G. Nikolaeva
  • L. M. Yudovich
  • N. T. Komyagin
  • A. I. Yanovskii
  • Yu. T. Struchkov
  • A. P. Kriven'ko
Article
  • 25 Downloads

Abstract

Catalytic hydroamination of methylene-2,2′-dicyclohexanone in the presence of substituted anilines or nitrobenzenes involves the formation of N-arylperhydroacridines. The stereoisomeric composition and yields of the latter are determined by the nature and position of the substituent in the aromatic ring of the aminating agent. The structure of isomeric N-arylperhydroacridines was established from data of 13C NMR spectroscopy and x-ray diffraction analysis.

Keywords

Spectroscopy Organic Chemistry Aniline Aromatic Ring Diffraction Analysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • T. G. Nikolaeva
    • 1
  • L. M. Yudovich
    • 1
  • N. T. Komyagin
    • 1
  • A. I. Yanovskii
    • 1
  • Yu. T. Struchkov
    • 1
  • A. P. Kriven'ko
    • 1
  1. 1.N. G. Chernyshevskii Saratov State UniversitySaratov

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