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Two paths for the formation of pyrimidines from sym-triazine

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of sym-triazine with the hydrochlorides of N-unsubstituted enaminones gives mixtures of 4-alkyl-5-acyl(ethoxycarbonyl)pyrimidines and 2,6-dialkyl-3,5-diacyl(ethoxycarbonyl)pyridines. The reaction mechanism was studied by means of the 15N-labelled compounds.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117977, Moscow

    S. P. Gromov, D. V. Yashunskii, R. S. Sagitullin & Yu. G. Bundel'

Authors
  1. S. P. Gromov
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  2. D. V. Yashunskii
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  3. R. S. Sagitullin
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  4. Yu. G. Bundel'
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1243–1249, September, 1992.

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Gromov, S.P., Yashunskii, D.V., Sagitullin, R.S. et al. Two paths for the formation of pyrimidines from sym-triazine. Chem Heterocycl Compd 28, 1054–1059 (1992). https://doi.org/10.1007/BF00531486

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  • DOI: https://doi.org/10.1007/BF00531486

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