Abstract
Treatment of 3-cyanotetrachloropyridine with sodium azide gives 2,4,6-triazido-3-chloro-5-cyanopyridine. This compound reacts regioselectively with norbomene to form an aziridinyl cydoadduct only at the azido group in position 4 of the pyridine ring.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1650–1652, December, 1993.
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Chapyshev, S.V. Synthesis and regioselective cycloaddition reaction of 2,4,6-triazido-3-chloro-5-cyanopyridine with norbornene. Chem Heterocycl Compd 29, 1426–1427 (1993). https://doi.org/10.1007/BF00531405
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DOI: https://doi.org/10.1007/BF00531405