Abstract
The reaction of methylamine with symmetrical 4,6,4′,6′-tetraphenyl-substituted 2-pyrylopolycarbocyanines, in which both a positions of the polymethine chain are linked to the β positions of the heterocyclic residues by trimethylene groups, was used to synthesize the corresponding pyridopyrylocyanines. The effect of trimethylene groupings in the 2-pyridocyanines on this transformation was examined. The principles involved in the color of the synthesized pyridopyrylocyanines were studied.
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M. A. Kudinova, V. V. Kurdyukov, A. A. Ishchenko, and A. I. Tolmachev, Khim. Geterotsikl. Soedin., No. 3, 339 (1992).
A. I. Tolmachev, N. A. Derevyanko, E. F. Karaban, and M. A. Kudinova, Khim. Geterotsikl. Soedin., No. 5, 612 (1975).
M. A. Kudinova, N. A. Derevyanko, G. G. Dyadyusha, A. A. Ishchenko, and A. I. Tolmachev, Khim. Geterotsikl. Soedin., No. 7, 898 (1980).
A. I. Tolmachev, N. A. Derevyanko, and A. A. Ishchenko, Khim. Geterotsikl. Soedin., No. 9, 1178 (1982).
G. Reynolds and F. Van Allen, J. Org. Chem., 34, 2736 (1969).
M. A. Kudinova, N. A. Derevyanko, G. G. Dyadyusha, A. A. Ishchenko, and A. I. Tolmachev, Khim. Geterotsikl. Soedin., No. 9, 1195 (1981).
A. A. Ishchenko, V. M. Zubarovskii, G. A. Gromova, and N. A. Derevyanko, Zh. Org. Khim., 23, 621 (1987).
A. A. Ishchenko, N. A. Derevyanko, and A. I. Tolmachev, Dokl. Akad. Nauk SSSR, 274, 106 (1984).
A. A. Ishchenko, M. A. Kudinova, Yu. L. Slominskii, and A. I. Tolmachev, Zh. Org. Khim., 22, 170 (1986).
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See [1] for Communication 29.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 345–348, March, 1992.
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Derevyanko, N.A., Ishchenko, A.A. & Tolmachev, A.I. Pyrylocyanines. 30. Unsymmetrical 4,6,4′,6′-tetraphenyl-substituted 2-pyrido-2-pyrylocyanines with trimethylene groupings in the chromophore. Chem Heterocycl Compd 28, 288–291 (1992). https://doi.org/10.1007/BF00529370
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DOI: https://doi.org/10.1007/BF00529370