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NMR parameters, isomerism, and conformational analysis of 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperid-6-yl)-pyridine

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The configurational and conformational features of the trans and cis isomers of 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperid-6-yl)pyridine, formed as by-products in the phenylation of β-picoline by phenyllithium, were established. The revealed stereospecificity of the 5JHH and 1JCH SSCCs may be utilized as an independent criterion in the conformational analysis of piperideine systems.

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Authors and Affiliations

  1. Russian University of the Friendship of Peoples, 117927, Moscow

    A. É. Aliev, A. A. Sinitsyna, L. M. Kirillova & N. S. Prostakov

Authors
  1. A. É. Aliev
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  2. A. A. Sinitsyna
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  3. L. M. Kirillova
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  4. N. S. Prostakov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 71–74, January, 1993.

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Aliev, A.É., Sinitsyna, A.A., Kirillova, L.M. et al. NMR parameters, isomerism, and conformational analysis of 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperid-6-yl)-pyridine. Chem Heterocycl Compd 29, 61–64 (1993). https://doi.org/10.1007/BF00528637

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  • DOI: https://doi.org/10.1007/BF00528637

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