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Synthesis and spectroscopic properties of soluble aza analogs of phthalocyanine and naphthalocyanine

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The syntheses of aryl-substituted octaaza analogs of phthalocyanine — tetra-2,3-(4,5-diphenylpyrazino)porphyrazin and its vanadyl complex — and also of the vanadyl complex of tetra-2,3-(4-phenylquinolino)porphyrazin — a tetraaza analog of naphthalocyanine — are described. A modified singlestage method for the synthesis of the previously reported tetra-2,3-(5-tert-butylpyrazino)porphyrazin is put forward. The electronic absorption spectra of the compounds synthesized have been studied in organic solvents and acid media — in sulfuric acid solution and in organic solvents with the addition of phenol or trichloroacetic acid.

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Authors and Affiliations

  1. Scientific-Research Institute of Organic Intermediates and Dyes, 103787, Moscow

    M. G. Gal'pern, S. V. Kudrevich & I. G. Novozhilova

Authors
  1. M. G. Gal'pern
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  2. S. V. Kudrevich
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  3. I. G. Novozhilova
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 58–63, January, 1993.

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Gal'pern, M.G., Kudrevich, S.V. & Novozhilova, I.G. Synthesis and spectroscopic properties of soluble aza analogs of phthalocyanine and naphthalocyanine. Chem Heterocycl Compd 29, 49–54 (1993). https://doi.org/10.1007/BF00528635

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  • DOI: https://doi.org/10.1007/BF00528635

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