Abstract
2-Ethynyl-substituted aziridines were obtained by the reaction of acetylenic β-amino and β-azido alcohols with triphenylphosphine and carbon tetrachloride in the presence of triethylamine. The cycloaddition of carbenes and diazomethane to an acetylenic imine was investigated. 2-Ethynylaziridines were obtained in the case of carbonylalkoxycarbenes. The regioselectivity of the cycloaddition of carbenes to an acetylenic imine is demonstrated.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 656–661, May, 1982.
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Shubina, Y.V., Tikhomirov, D.A. & Eremeev, A.V. Synthesis of 2-ethynylaziridines. Chem Heterocycl Compd 18, 494–498 (1982). https://doi.org/10.1007/BF00526085
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DOI: https://doi.org/10.1007/BF00526085