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Reactions of 4-amino-1,3,5-dithiazine with ammonia and amines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It is shown that selective replacement of the sulfur atom in the 3 position by a nitrogen atom, which leads to 2,6-dimethyl-4-amino-3H-2,6-dihydro-1,3,5-thiadiazine, occurs when 2H,6H-2,6-dimethyl-4-amino-1,3,5-dithiazine is treated with ammonium hydroxide. Under the same conditions, amines cause profound destruction of 2H,6H-2,6-dimethyl-4-amino-1,3,5-dithiazine with the production of thiourea.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033, Irkutsk

    G. M. Gavrilova, B. A. Trofimov, V. I. Gostevskaya & S. V. Amosova

Authors
  1. G. M. Gavrilova
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  2. B. A. Trofimov
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  3. V. I. Gostevskaya
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  4. S. V. Amosova
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 652–655, May, 1982.

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Gavrilova, G.M., Trofimov, B.A., Gostevskaya, V.I. et al. Reactions of 4-amino-1,3,5-dithiazine with ammonia and amines. Chem Heterocycl Compd 18, 491–494 (1982). https://doi.org/10.1007/BF00526084

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  • DOI: https://doi.org/10.1007/BF00526084

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