Abstract
The homogeneous isotope exchange of O-, N-, and S-containing heterocyclic compounds and a number of hydrocarbons with D2O in the presence of platinum (II) complexes, viz., potassium tetrachloroplatinite, platinum(II) monochlorodiethylene-triaminepentaacetate, chlorodiethylenediamineplatinum(II), dichloroethylenediamineplatinum(II), dichloroethylenediaminetetraacetatoplatinum(II) and, in the case of hydrocarbons, potassium tetrachloroplatinite, was investigated. The M factors were calculated for the H-D exchange of the hydrocarbons. It was shown that the H-D exchange of benzene has multiple character, whereas it has stepwise character in the case of cyclohexane.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 754–760, June, 1983.
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Karakhanov, É.A., Dedov, A.G., Loktev, A.S. et al. Homogeneous H-D exchange of heterocycles and some hydrocarbons with D2O in the presence of pt(II) complexes. Chem Heterocycl Compd 19, 602–607 (1983). https://doi.org/10.1007/BF00523068
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DOI: https://doi.org/10.1007/BF00523068