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Mass spectrometric study of the stereoisomers of 2-furyl- and 2-phenyldecahydro-4-quinolinone and their tertiary alcohols

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A study was carried out on the major pathways for the decomposition of stereoisomers of 2-furyl- and 2-phenyldecahydro-4-quinolinone and their tertiary alcohol derivatives upon electron impact. The elemental composition of the characteristic ions was determined by high-resolution mass spectrometry. The introduction of a heavy substituent at C(2) leads to marked changes in the directions of the major fragmentation pathways of decahydroquinoline. The dependence of the probability for the formation of characteristic ions on the molecular geometry in the stereoisomer series was demonstrated.

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Authors and Affiliations

  1. Institute of Chemical Sciences, Academy of Sciences of the Kazakh SSR, 480100, Alma-Ata

    A. E. Lyuts, V. V. Zamkova, O. V. Agashkin, K. D. Praliev, O. T. Zhilkibaev & M. Z. Esenalieva

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  1. A. E. Lyuts
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  2. V. V. Zamkova
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  3. O. V. Agashkin
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  4. K. D. Praliev
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  5. O. T. Zhilkibaev
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  6. M. Z. Esenalieva
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 242–247, February, 1986.

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Lyuts, A.E., Zamkova, V.V., Agashkin, O.V. et al. Mass spectrometric study of the stereoisomers of 2-furyl- and 2-phenyldecahydro-4-quinolinone and their tertiary alcohols. Chem Heterocycl Compd 22, 195–199 (1986). https://doi.org/10.1007/BF00519943

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  • DOI: https://doi.org/10.1007/BF00519943

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