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Reaction of 2-methyl-5,6-dihydro-2H-pyran with dichlorocarbene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Upon treatment of 2-methyl-5,6-dihydro-2H-pyran with dichlorocarbene there are formed products of addition to the double bond and insertion at the C-H bond giving cis- and trans-7,7-dichloro-2-methyl-3-oxabicyclo[4.1.0]heptane and 2-dichloromethyl-2-methyl-5,6-dihydro-2H-pyran.

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Literature cited

  1. E. E. Schweizer and W. E. Parham, J. Amer. Chem. Soc., 82, 4085 (1960).

    Google Scholar 

  2. J. C. Anderson and D. J. Lindsay, Tetrahedron, 20, 2021 (1964).

    Google Scholar 

  3. J. C. Anderson and C. B. Reese, Chem. Ind., No. 3, 575 (1963).

    Google Scholar 

  4. A. A. Gevorkyan, N. M. Khizantsyan, P. I. Kazaryan, and G. A. Panosyan, Khim. Geterotsikl Soedin., No. 2, 167 (1981).

    Google Scholar 

  5. V. Kirmse, Chemistry of Carbenes [Russian translation], Mir, Moscow, (1966), p. 201.

    Google Scholar 

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Authors and Affiliations

  1. Bashkir State University, 450074, Ufa

    U. G. Ibatullin, T. F. Petrushina, R. R. Gataullin & M. G. Safarov

Authors
  1. U. G. Ibatullin
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  2. T. F. Petrushina
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  3. R. R. Gataullin
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  4. M. G. Safarov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 190–191, February, 1986.

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Ibatullin, U.G., Petrushina, T.F., Gataullin, R.R. et al. Reaction of 2-methyl-5,6-dihydro-2H-pyran with dichlorocarbene. Chem Heterocycl Compd 22, 147–148 (1986). https://doi.org/10.1007/BF00519933

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  • DOI: https://doi.org/10.1007/BF00519933

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