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Synthesis of pyridinium salts by the reaction of α, β-unsaturated ketones, primary amines, and compounds with labile hydrogen atoms

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of α, β-unsaturated ketones or Mannich bases of ketones with primary aromatic amines and ketones (monoketones or dimedone) in the presence of polyhalo-alkanes leads to pyridinium, 5,6,7,8-tetrahydroquinolinium, or sym-octahydroacridinium salts. The reaction of benxalcyclohexanone with primary aromatic amines and malonodinitrile makes it possible to obtain 2-amino-3-cyano-5,6,7,8-tetrahydroquinolinium salts.

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Authors and Affiliations

  1. Far Eastern State University, 690652, Vladivostok

    V. A. Kaminskii, G. Ya. Shevchuk & M. N. Tilichenko

Authors
  1. V. A. Kaminskii
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  2. G. Ya. Shevchuk
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  3. M. N. Tilichenko
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1060–1064, August, 1985.

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Kaminskii, V.A., Shevchuk, G.Y. & Tilichenko, M.N. Synthesis of pyridinium salts by the reaction of α, β-unsaturated ketones, primary amines, and compounds with labile hydrogen atoms. Chem Heterocycl Compd 21, 883–887 (1985). https://doi.org/10.1007/BF00519815

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  • DOI: https://doi.org/10.1007/BF00519815

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