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Porphyrins. 20. Interaction of 2-formyl-5,10,15,20-tetraphenylporphyrin with ch acids

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Abstract

The reactions of 2-formyl-5,10,15-20-tetraphenylporphyrin (Ia) with nitromethane and of its Cu complex (Ib) with nitromethane, malonic acid, and its esters have been investigated. On interacting porphyrins (Ia,b) with nitromethane in AcOH/BuNH2 the 2-(2-nitrovinyl)porphyrins (IIa,b) were formed, in liquid NH3 the nitroalcohols (IIIa,b) were formed, and in DMF/BuNH2 the dinitro derivatives (IVa,b) were formed. The interaction of porphyrin (Ib) with malonic acid and its esters led to the corresponding condensation products in high yield.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, 117234, Moscow

    I. G. Rish, V. S. Pshezhetskii, K. A. Askarov & G. V. Ponomarev

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  1. I. G. Rish
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  2. V. S. Pshezhetskii
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  3. K. A. Askarov
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  4. G. V. Ponomarev
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Additional information

For Communication 19 see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 936–940, July, 1985.

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Rish, I.G., Pshezhetskii, V.S., Askarov, K.A. et al. Porphyrins. 20. Interaction of 2-formyl-5,10,15,20-tetraphenylporphyrin with ch acids. Chem Heterocycl Compd 21, 777–781 (1985). https://doi.org/10.1007/BF00519146

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  • DOI: https://doi.org/10.1007/BF00519146

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