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Chemistry of Heterocyclic Compounds

, Volume 19, Issue 8, pp 879–882 | Cite as

Radical meso-alkylation of vanadyletioporphyrin

  • Z. P. Altukhova
  • V. R. Antipenkov
  • V. I. Titov
Article
  • 25 Downloads

Abstract

The possibility of the meso-alkylation of vanadyletioporphyrin (25–30% yields) by its reaction with alkyl bromides [C(6)-C(12)] in the presence of finely dispersed silver metal at 150–180 °C in an argon atmosphere with the formation of 5,15-dialkylvanadyletioporphyrins and 5,15-dialkyl-5,15-dihydrovanadyletioporphyrins as side products is demonstrated.

Keywords

Atmosphere Argon Bromide Organic Chemistry Argon Atmosphere 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • Z. P. Altukhova
    • 1
  • V. R. Antipenkov
    • 1
  • V. I. Titov
    • 1
  1. 1.Siberian Branch, Institute of Petroleum ChemistryAcademy of Sciences of the USSRTomsk

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