Chemistry of Heterocyclic Compounds

, Volume 19, Issue 8, pp 879–882 | Cite as

Radical meso-alkylation of vanadyletioporphyrin

  • Z. P. Altukhova
  • V. R. Antipenkov
  • V. I. Titov


The possibility of the meso-alkylation of vanadyletioporphyrin (25–30% yields) by its reaction with alkyl bromides [C(6)-C(12)] in the presence of finely dispersed silver metal at 150–180 °C in an argon atmosphere with the formation of 5,15-dialkylvanadyletioporphyrins and 5,15-dialkyl-5,15-dihydrovanadyletioporphyrins as side products is demonstrated.


Atmosphere Argon Bromide Organic Chemistry Argon Atmosphere 
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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • Z. P. Altukhova
    • 1
  • V. R. Antipenkov
    • 1
  • V. I. Titov
    • 1
  1. 1.Siberian Branch, Institute of Petroleum ChemistryAcademy of Sciences of the USSRTomsk

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