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Synthesis of cyclic saturated sulfones by the catalytic reduction of unsaturated compounds

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The synthesis of sulfones of thiacyclohexanes, thiadecalins, and perhydrothioxanthenes by the catalytic hydrogenation of the corresponding α,β-unsaturated cyclic sulfones in the presence of palladium on carbon was developed. The effects of the temperature conditions, excess hydrogen pressure, the nature of the grouping in the 4 position of the heteroring, and the degree of shielding of the double bond on the process were established.

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Authors and Affiliations

  1. N. G. Chernyshevskii Saratov State University, 410601, Saratov

    V. G. Kharchenko, A. M. Plotnikov & A. D. Shebaldova

Authors
  1. V. G. Kharchenko
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  2. A. M. Plotnikov
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  3. A. D. Shebaldova
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1058–1061, August, 1983.

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Kharchenko, V.G., Plotnikov, A.M. & Shebaldova, A.D. Synthesis of cyclic saturated sulfones by the catalytic reduction of unsaturated compounds. Chem Heterocycl Compd 19, 848–850 (1983). https://doi.org/10.1007/BF00516447

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  • DOI: https://doi.org/10.1007/BF00516447

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